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Publications

Publications by Paulo Soares Santos

2021

Advances in Plasmonic Sensing at the NIR-A Review

Authors
Dos Santos, PSS; De Almeida, JMMM; Pastoriza Santos, I; Coelho, LCC;

Publication
SENSORS

Abstract
Surface plasmon resonance (SPR) and localized surface plasmon resonance (LSPR) are among the most common and powerful label-free refractive index-based biosensing techniques available nowadays. Focusing on LSPR sensors, their performance is highly dependent on the size, shape, and nature of the nanomaterial employed. Indeed, the tailoring of those parameters allows the development of LSPR sensors with a tunable wavelength range between the ultra-violet (UV) and near infra-red (NIR). Furthermore, dealing with LSPR along optical fiber technology, with their low attenuation coefficients at NIR, allow for the possibility to create ultra-sensitive and long-range sensing networks to be deployed in a variety of both biological and chemical sensors. This work provides a detailed review of the key science underpinning such systems as well as recent progress in the development of several LSPR-based biosensors in the NIR wavelengths, including an overview of the LSPR phenomena along recent developments in the field of nanomaterials and nanostructure development towards NIR sensing. The review ends with a consideration of key advances in terms of nanostructure characteristics for LSPR sensing and prospects for future research and advances in this field.

2021

Spectral Reconstruction and Bayesian Model Framework for Characterization of Long Period Fiber Gratings

Authors
Dias, B; Santos, P; Jorge, PAS; de Almeida, JMMM; Coelho, LCC;

Publication
IEEE INSTRUMENTATION & MEASUREMENT MAGAZINE

Abstract
The use of Long-Period Fiber Gratings (LPFGs) as sensors has been thoroughly researched, given the multitude of parameters these structures can monitor by themselves (such as temperature, strain, curvature) and the potential for combination with other materials that allow for monitoring of parameters such as humidity, pH and chemical concentration, at a low price and with easy fabrication processes available. This interest has increased the need for the development of interrogation systems for these sensors, particularly in the C-band spectral region. Given the cost and physical limitations (such as size and weight) of traditional solutions like Optical Spectrum Analyzers (OSA), the development of low-cost approaches for LPFG spectral analysis became an important topic that needed further development. The development of a simple curve fitting routine for LPFG spectra is reported in this article, along with a framework for automatic detection of certain physical phenomena such as corrosion and the presence of chemical species, among others.

2021

Optical Biosensor for the Detection of Hydrogen Peroxide in Milk

Authors
Vasconcelos, H; Matias, A; Jorge, P; Saraiva, C; Mendes, J; Araújo, J; Dias, B; Santos, P; Almeida, JMMM; Coelho, LCC;

Publication
Chemistry Proceedings

Abstract
Over the years, the food industry’s concern to provide safe food that does not cause harm or illness to consumers has increased. The growing demand for the detection of compounds that can contaminate food is increasingly important. Hydrogen peroxide is frequently used as a substance to control the growth of microorganisms in milk, thus increasing its shelf life. Here, a strategy is presented for the detection of hydrogen peroxide as a milk adulterant, using a single shot membrane sensor. The lowest concentration measured with this technique was 0.002% w/w of H2O2 in semi-fat milk.

2022

Study of LSPR Spectral Analysis Techniques on SPR Optical Fiber Sensors

Authors
Dos Santos, PSS; de Almeida, JMMM; Coelho, LCC;

Publication
U.Porto Journal of Engineering

Abstract
Nanoparticles create localized surface plasmonic resonances (LSPR) with lower surrounding refractive index (SRI) sensitivities than their propagating SPR counterpart, originated in thin films. Historically, LSPR SRI sensitivities enhancements were achieved through spectral analysis methods that focus on unique spectral features. Herein, a study using that methodology was applied on SPR devices resulting in an increased sensitivity to SRI. It was found that by applying the inflection point method on optical fiber SPR sensors resulted in both sensitivity and resolution increments up to 44 and 35 %, respectively, in the SRI range from 1.3333 to 1.4150. Thus, successfully improving sensing capabilities of SPR based optical fiber sensors. © 2022, Universidade do Porto - Faculdade de Engenharia. All rights reserved.

2022

Strongly coupled plasmonic systems on optical fiber sensors: A study on nanomaterial properties

Authors
Dos Santos, PSS; Mendes, J; Dias, B; Pastoriza Santos, I; De Almeida, JMMM; Coelho, LCC;

Publication
Journal of Physics: Conference Series

Abstract
New paths to increase the sensing performance of plasmonic sensors have been reported in recent years. There are several methodologies to achieve such purpose, namely by optimizing the nanostructure, nanomaterial and even the sensing platform. Recently the use nanoparticles over plasmonic thin films have been reported and shown sensitivity enhancement, when compared to a bare thin film. Nevertheless, a nanomaterial combination between NP and thin film has not been studied. In this work it was studied such plasmonic materials in order to optimize not only refractometric sensitivity but also decrease the resultant plasmonic band width. It was found that for Au, Ag and Cu thin films, the deposition of plasmonic nanoparticles resulted in an overall refractometric sensitivity and figure of merit (FOM) increase. The larger FOM increase was obtained for the Ag thin film, from 42 to 162 when coupled to Si nanoparticles. The greater sensitivity increase was achieved for a Cu thin film coupled to a Si nanoparticle, with an increase from 1745 to 3230 nm/RIU. © Published under licence by IOP Publishing Ltd.

2022

Development of a Low-Cost Interrogation System Using a MEMS Fabry-Pérot Tunable Filter

Authors
Araújo, JCC; Dias, B; Dos Santos, PSS; De Almeida, JMMM; Coelho, LCC;

Publication
Journal of Physics: Conference Series

Abstract
The interrogation of optic fiber sensors usually relies in complex and costly equipment with low portability due to their size such as Optical Spectrum Analyzers (OSA) or high-resolution spectrometers. Because of this, micro spectrometer devices, such as Micro-Electromechanical Systems (MEMS) with Fabry-Pérot tunable filters, are emerging as simpler and compact alternatives capable of being used to acquire spectral information in a wide wavelength band. In this work it is described the development of an interrogation system capable of infrared spectroscopy using a MEMS Fabry-Pérot Interferometer (MEMS-FPI) with a spectral response in the 1350nm to 1650nm range. Its performance is tested with the interrogation of long period fiber gratings both as a refractive index sensor and as a temperature sensor. Deconvolution techniques such as Wiener filtering are used to reduce the impact of the tunable filter's impulse response in the measured signal. Results are comparable to those obtained using a typical OSA which shows the system's potential as a cheaper and more transportable alternative. © Published under licence by IOP Publishing Ltd.

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