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Publications

Publications by Paulo Caldas

2006

Applications of quantum dots in optical fiber luminescent oxygen sensors

Authors
Jorge, PAS; Mayeh, M; Benrashid, R; Caldas, P; Santos, JL; Farahi, F;

Publication
APPLIED OPTICS

Abstract
The potential applications of luminescent semiconductor nanocrystals to optical oxygen sensing are explored. The suitability of quantum dots to provide a reference signal in luminescence-based chemical sensors is addressed. A CdSe-ZnS nanocrystal, with an emission peak at 520 nm, is used to provide a reference signal. Measurements of oxygen concentration, which are based on the dynamic quenching of the luminescence of a ruthenium complex, are performed. Both the dye and the nanocrystal are immobilized in a solgel matrix and are excited by a blue LED. Experimental results show that the ratio between the reference and the sensor signals is highly insensitive to fluctuations of the excitation optical power. The use of CdTe, near-infrared quantum dots with an emission wavelength of 680 run, in combination with a ruthenium complex to provide a new mechanism for oxygen sensing, is investigated. The possibility of creating oxygen sensitivity in different spectral regions is demonstrated. The results obtained clearly show that this technique can be applied to develop a wavelength division multiplexed system of oxygen sensors. (c) 2006 Optical Society of America.

2009

Modal Interferometer Based on ARROW Fiber for Strain and Temperature Measurement

Authors
Aref, SH; Frazao, O; Caldas, P; Ferreira, LA; Araujo, FM; Santos, JL; Latifi, H; Foy, P; Hawkins, T; Ballato, J; Her, T; Farahi, F;

Publication
IEEE PHOTONICS TECHNOLOGY LETTERS

Abstract
In this letter, interferometric sensors based on antiresonance reflecting optical waveguide (ARROW) fibers were developed, and used to sense strain and temperature. Two types of solid-ore ARROW fibers were considered and signal demodulation was achieved by using the white light interferometric technique. The ARROW fibers have two rings of high index rods arranged in a hexagonal structure with a lattice constant of 6 m. The different sizes of the rods cause different measurand sensitivities for the two fibers. Resolutions of +/- 1.1 mu epsilon and +/- 0.07 degrees C were achieved for strain and temperature, respectively.

2009

Geometrical effects on the refractive index sensitivity of Mach-Zehnder fibre modal interferometers based on long-period gratings

Authors
Caldas, P; Jorge, PAS; Araujo, FM; Ferreira, LA; Rego, G; Santos, JL;

Publication
MEASUREMENT SCIENCE & TECHNOLOGY

Abstract
In this work a modal interferometer based on arc-induced long-period gratings (LPGs) in a Mach-Zehnder configuration is evaluated as a sensing structure for environmental refractive index measurement. To interrogate this sensing device, coherence addressing and pseudo-heterodyne processing were used. The influence of geometric effects such as stretching, bending and twisting the interferometer on the sensitivity to refractive index changes was studied. It is shown that due to the antisymmetric nature of cladding modes in arc-induced LPGs, it is possible to tune the system sensitivity to external refractive index by simple mechanical action. The experimental results show that it is possible to tune the sensitivity to external refractive index by more than 50% by control of the curvature in the Mach-Zehnder interferometer.

2006

Quantum dots as self-referenced optical fibre temperature probes for luminescent chemical sensors

Authors
Jorge, PAS; Mayeh, M; Benrashid, R; Caldas, P; Santos, JL; Farahi, F;

Publication
MEASUREMENT SCIENCE & TECHNOLOGY

Abstract
The use of semiconductor nano-particles as temperature probes in luminescence chemical sensing applications is addressed. Temperature changes the intensity, the peak wavelength and the spectral width of the quantum dots luminescent emission in a linear and reversible way. Results are presented that show the feasibility of implementing a self-referenced intensity-based sensor to perform temperature measurements independent of the optical power level in the sensing system. A resolution of 0.3 degrees C was achieved. In addition, it is demonstrated that self-referenced temperature measurements at multiple points could be performed using reflection or transmission based optical fibre configurations.

2004

Optical fiber probes for fluorescence based oxygen sensing

Authors
Jorge, PAS; Caldas, P; Rosa, CC; Oliva, AG; Santos, JL;

Publication
SENSORS AND ACTUATORS B-CHEMICAL

Abstract
An optical fiber sensing system, for monitoring oxygen aiming in vivo nuclear magnetic resonance (NMR) applications is presented. Oxygen detection is based on the dynamic quenching of the fluorescence of a ruthenium complex trapped in the porous structure of a sol-gel silica film. Oxygen concentration is determined by phase-modulation fluorometry. Preliminary results concerning the characterization of doped sol-gel thin films deposited by dip coating in glass slides and in optical fiber probes are presented. Four different probe configurations are tested and compared. Best results are obtained with a fiber taper configuration which shows reproducibility and best excitation efficiency. This structure is fully characterized and some considerations regarding optimal fiber optical sensing probes for 02 detection are addressed.

2007

In-fibre Mach-Zehnder configuration based on fibre multimode interference structure combined with a long period grating - art. no. 66192H

Authors
Frazao, O; Viegas, J; Caldas, P; Araujo, FM; Ferreira, LA; Santos, JL; Farahi, F;

Publication
Third European Workshop on Optical Fibre Sensors

Abstract
A novel Mach-Zehnder interferometer based on a fibre multimode interference structure combined with a long period fibre grating is proposed. The multimode interference is achieved through the use of a multimode fibre section splices between two sin-le-mode fibres, with a length adjusted to couple a fraction of light into the cladding modes. A LP placed after the multimode fibre couples light back into the fibre core completing the Mach-Zehnder interferometer. The novel configuration was demonstrated as a bending sensor.

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