Abstract

Abstract
Associated with the exploitation of metallic minerals in Europe during the 20th century, several mining areas were abandoned without adequate environmental intervention. Furthermore, these areas lack studies to characterize the impact of pollution on the hydrogeological system. The area surrounding the tungsten mine of Regoufe, in northern Portugal, is one such area exploited during the Second World War. The accumulation of sulfide-rich tailings may have caused an acid mine drainage (AMD), where the leaching processes caused by seepage water led to soil contamination, evidenced by its acid character and anomalous concentrations of some Potentially Toxic Elements (PTE) reported in previous studies. The present research proposes an innovative approach that seeks the integration of different geophysical techniques to characterize the impact of mining activity on the subsurface. Electrical resistivity (ER) and electromagnetic (EM) were used to measure subsurface electrical properties. In addition, seismic refraction and Multichannel Analysis of Surface Waves (MASW) were performed to characterize the geometry, depth, and geomechanical behavior of the soil and rock bodies. The integration of these techniques allowed the interpretation of hydrogeological sections and a 3D resistivity volume to gain insight into the distribution of potentially contaminating fluids and tailings material present in the mining valley.

Abstract
Advancement and opportunity in the Internet of Things (IoT) and circular economy are pushing the technologies required to develop eco-friendly memory devices, computing devices, advanced sensors, and actuators. In this manuscript, a thermally cycled lithium niobate pyroelectric crystal is used to store the surface charges in different dielectric samples (Kapton, Parafilm, and Teflon). Charge storing parameters, such as the effect of temperature ramp, the gap between the dielectric-to-pyroelectric, and the effect of charging cycles, were studied to understand the surface charge formation on dielectric samples. Pyroelectrically charged dielectrics showed a surface potential of up to 400 V, with a linear dependence on the thermal gradient of the pyroelectric crystal. The charged surface showed good charge storage uniformity and stability at high temperatures (90 degrees C) and relative humidity (>85%). Using the pyroelectrically charged dielectrics, wearable motion sensors offering output signals in the range of tens of millivolts and a digital flexible invisible memory encoding with polarity switched (positive and negative charges) electrostatic bits are demonstrated.

Abstract
A versatile, miniaturized, cost-effective, low-power wave profile and tide monitoring system, capable of long-term and scalable deployment, was developed to integrate pressure and temperature sensors in an RS485 network, for standalone operation with organized memory or real-time shared data monitoring. The pressure and temperature sensors are controlled by low-power microcontrollers, that communicate the data periodically to a datalogger, that depending on the application, store it in a removable SD card or send it to a server via Wi-Fi. The data is then analyzed to compensate for the loss in amplitude sensitivity according to the sensor's depth. The wave profile can be sampled at a maximum rate of 100 Hz, with a 1 cm resolution. The system was tested successfully in real-life conditions, in rivers Douro and Cavado, and off the coast of Viana do Castelo.

Abstract
Oceans all over the world are an important way of sustainability in the lives of many people and have a high impact on the economy of most of the coastal countries. With the growth of underwater activity provided by the development of autonomous and remotely controlled vehicles and with the appearance of new underwater sensors, there is also a need to develop and design more robust underwater wireless networks to provide better and faster communications among the devices connected to the network. Nowadays several technologies provide wireless underwater communications. In this work, we address acoustic technology and the implementation of an acoustic communication system which applies a version of frequency modulation. The main goal of this work is to study the 4-FSK modulation technique and verify the efficiency of the communication system according to variables such as communication distance and baud rate. This implementation uses FPGA systems and Xilinx Vitis Model Composer software and MATLAB Simulink software for simulation. The developed communication system was tested in a controlled environment at two stages: aquarium and pool. The tests were carried out transmitting at 3 different baud rates (40, 100 and 200 kbps) in a distance of 100 cm in the aquarium and 5 meters in the pool.

Abstract
Implementing Artificial Reefs (AR) is seen as a worldwide strategy to overcome the problematic environmental impacts due to climate change, overfishing and other activities that damage natural habitats and ecosystems. The production and deployment of ARs involve a series of technical challenges and this work explores a possible alternative solution to overcome some of these challenges. This work addresses a new system for building underwater modular structures integrating monitoring sensors, exploring the potential that Flat Knitted textiles have when specifically designed and used as Knitted Textile Preforms (KTPs) for concrete filling. The casting of AR modules directly in their final position, underwater, brings new paradigms to the design and production of ARs clusters with more complex geometries and geometrical continuity between modules. This manuscript is dedicated to the analysis of variables such as injection pressure and its variations during filling and curing, respectively, as well as the textile structure and geometrical design. It also addresses the possibilities of the technology to embed environmental sensors, which will add functions to the AR structure.