Abstract
Topological photonics, leveraging concepts from condensed matter physics, offers transformative potential in the design of robust optical systems. This study investigates the integration of topologically protected edge states into plasmonic nanostructures for enhanced optical sensing. We propose a toy model comprising two chains of metallic filaments forming a one-dimensional plasmonic crystal with diatomic-like unit cells, positioned on a waveguide. The system exhibits edge states localized at the boundaries and a central defect, supported by the Su-Schrieffer-Heeger (SSH) model. These edge states, characterized by significant electric field enhancement and topological robustness, are shown to overcome key limitations in traditional plasmonic sensors, including sensitivity to noise and fabrication inconsistencies. Through coupled mode theory, we demonstrate the potential for strong coupling between plasmonic and guided optical modes, offering pathways for improved interferometric sensing schemes. This work highlights the applicability of topological photonics in advancing optical sensors.

Abstract
This study explores the application of machine learning algorithms to optimize the geometry of the plasmonic layer in a surface plasmon resonance photonic crystal fiber sensor. By leveraging the simplicity of linear regression ( LR) alongside the advanced predictive capabilities of the gradient boosted regression (GBR) algorithm, the proposed approach enables accurate prediction and optimization of the plasmonic layer's configuration to achieve a desired spectral response. The integration of LR and GBR with computational simulations yielded impressive results, with an R-2 exceeding 0.97 across all analyzed variables. Moreover, the predictive accuracy demonstrated a remarkably low margin of error, epsilon < 10(-15). This combination of methods provides a robust and efficient pathway for optimizing sensor design, ensuring enhanced performance and reliability in practical applications.

Abstract
In our study, we conducted a thorough analysis of the spectral characteristics of a D-shaped surface plasmon resonance (SPR) photonic crystal fiber (PCF) refractive index sensor, incorporating a full width at half maximum (FWHM) analysis. We explored four distinct plasmonic materials—silver (Ag), gold (Au), Ga-doped zinc oxide (GZO), and an Ag-nanowire metamaterial—to understand their impact on sensor performance. Our investigation encompassed a comprehensive theoretical modeling and analysis, aiming to unravel the intricate relationship between material composition, sensor geometry, and spectral response. By scrutinizing the sensing properties offered by each material, we laid the groundwork for designing multiplasmonic resonance sensors. Our findings provide valuable insights into how different materials can be harnessed to tailor SPR sensing platforms for diverse applications and environmental conditions, fostering the development of advanced and adaptable detection systems. This research not only advances our understanding of the fundamental principles governing SPR sensor performance but also underscores the potential for leveraging varied plasmonic materials to engineer bespoke sensing solutions optimized for specific requirements and performance metrics. © 2025 SBMO/SBMag.

Abstract
Carbon dioxide (CO2) plays a crucial role in the biosphere, acting as an indicator of anthropogenic activity. Its monitoring is fundamental for controlling air and water quality, preserving the environment and optimizing industrial processes. The preparation of a bright fluorescent scaffold, named rhodol, was optimized by employing microwave heating as an alternative heating source, achieving shorter reaction times and higher yields. Structural characterization was performed by nuclear magnetic resonance (NMR) and high-resolution mass spectrometry (HRMS-ESI). Its application to produce a fluorescent optical membrane for monitoring CO2 in gas (gCO2) and in water (dCO2) was explored. Two different setups are used for this purpose, and in both, the same optical response is observed: the membrane's fluorescence intensity decreases as the CO2 concentration increases. The sensor's reliability for dCO2 is demonstrated through testing concentrations ranging from 1 ppm to 100 ppm with minimal photobleaching (0.0026 dB) over 7500 data points with an integration time of 200 ms each. The sensor performance for dCO2 evaluation exhibits an experimental error of +/- 1.81 ppm, a response time of 2 min, a limit of detection of 0.6 ppm and a Stokes-shift of 90 nm for concentrations between 1 and 100 ppm. Monitoring of gCO2 using this membrane is hindered by changes in relative humidity (RH), hence the results for concentration between 0.3 % and 100 % of gCO2 were achieved by maintaining a consistent high value of RH. Our findings highlight the effectiveness of the optimized rhodol synthesis and its application in an optical membrane for reliable monitoring of CO2 in various environmental conditions.

Abstract
The phase-matching conditions for exciting surface plasmon resonances (SPR) in plasmonic films are typically satisfied via prism, optical fibers or grating-assisted coupling. We recently showed that plasmonic nanospheres can act as local emitters, exciting SPR waves on thin films-termed nanoparticle-induced SPR (NPI-SPR). This structure holds promise for sensing, but the effects of optical fiber geometry and nanoparticle anisotropy on the response were unexplored. This study examines these factors, showing that an etched multimode fiber with a 200 mu m core diameter, taper ratio of 4, and etching angle of 20 degrees optimizes interaction with plasmonic nanoparticles. Tuning the nanoparticle aspect ratio from 1 to 3 shifts the NPI-SPR band from 780 to 1580 nm, with excitation highly dependent on the incident light angle. Notably, for light incident parallel to the film plane, a refractive index sensitivity exceeding 1000 nm/RIU is achieved. This efficient light emission combines the field locality enhancements of plasmonic nanoparticle-on-film structures with the emission efficiency of plasmonic nanoantennas, advancing plasmonic optical fiber chemical and biosensors.

Abstract
This study investigates the fabrication of plasmonic optical fiber sensors for glyphosate detection, employing silver thin film coatings deposited via the Tollens' reaction and further enhanced with protective gold plating. Silver films were produced through electroless deposition, forming rough plasmonic surfaces with localized hotspots that amplify the electromagnetic field. Surface roughness effects on the creation of hotspots were first evaluated numerically using the finite element method (FEM) and later experimentally assessed the impact on optical response. Furthermore, to address the inherent susceptibility of silver to oxidation and corrosion, a gold plating was applied using the Kirkendall effect, selectively replacing surface silver atoms with gold. This approach significantly improved the chemical stability of the sensors while preserving their plasmonic properties. This configuration was applied in developing a biosensor, using aptamers, for detecting glyphosate in concentrations ranging from 10(-1) to 10(4) mu g/L. The results demonstrated a sensitivity of 25.08 +/- 0.22 nm/(mu g/L) and a limit of detection (LOD) of 0.04 mu g/L, nearly ten times lower than the European Union's safety limit for glyphosate. Experimental results highlight the potential of this fabrication approach for developing sensitive, stable, and scalable plasmonic sensors tailored for environmental and agricultural monitoring applications.