2025
Authors
Teixeira, J; Lopes, T; Capela, D; Monteiro, CS; Guimaraes, D; Lima, A; Jorge, PAS; Silva, NA;
Publication
SCIENTIFIC REPORTS
Abstract
Spectral Imaging techniques such as Laser-induced Breakdown Spectroscopy (LIBS) and Raman Spectroscopy (RS) enable the localized acquisition of spectral data, providing insights into the presence, quantity, and spatial distribution of chemical elements or molecules within a sample. This significantly expands the accessible information compared to conventional imaging approaches such as machine vision. However, despite its potential, spectral imaging also faces specific challenges depending on the limitations of the spectroscopy technique used, such as signal saturation, matrix interferences, fluorescence, or background emission. To address these challenges, this work explores the potential of using techniques from conventional RGB imaging to enhance the dynamic range of spectral imaging. Drawing inspiration from multi-exposure fusion techniques, we propose an algorithm that calculates a global weight map using exposure and contrast metrics. This map is then used to merge datasets acquired with the same technique under distinct acquisition conditions. With case studies focused on LIBS and Raman Imaging, we demonstrate the potential of our approach to enhance the quality of spectral data, mitigating the impact of the aforementioned limitations. Results show a consistent improvement in overall contrast and peak signal-to-noise ratios of the merged images compared to single-condition images. Additionally, from the application perspective, we also discuss the impact of our approach on sample classification problems. The results indicate that LIBS-based classification of Li-bearing minerals (with Raman serving as the ground truth), is significantly improved when using merged images, reinforcing the advantages of the proposed solution for practical applications.
2025
Authors
Capela, D; Lopes, T; Dias, F; Ferreira, MFS; Teixeira, J; Lima, A; Jorge, PAS; Silva, NA; Guimaraes, D;
Publication
SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY
Abstract
Mineral identification is a challenging task in geological sciences, which often implies multiple analyses of the physical and chemical properties of the samples for an accurate result. This task is particularly critical for the mining industry, where proper and fast mineral identification may translate into major efficiency and performance gains, such as in the case of the lithium mining industry. In this study, a mineral identification algorithm optimized for analyzing lithium-bearing samples using Laser-induced breakdown spectroscopy (LIBS) imaging, is put to the test with a set of representative samples. The algorithm incorporates advanced spectral processing techniques-baseline removal, Gaussian filtering, and data normalization-alongside unsupervised clustering to generate interpretable classification maps and auxiliary charts. These enhancements facilitate rapid and precise labelling of mineral compositions, significantly improving the interpretability and interactivity of the user interface. Extensive testing on diverse mineral samples with varying complexities confirmed the algorithm's robustness and broad applicability. Challenges related to sample granulometry and LIBS resolution were identified, suggesting future directions for optimizing system resolution to enhance classification accuracy in complex mineral matrices. The integration of this advanced algorithm with LIBS technology holds the potential to accelerate the mineral evaluation, paving the way for more efficient and sustainable mineral exploration.
2025
Authors
Lopes, T; Cavaco, R; Capela, D; Dias, F; Teixeira, J; Monteiro, CS; Lima, A; Guimaraes, D; Jorge, PAS; Silva, NA;
Publication
TALANTA
Abstract
Combining data from different sensing modalities has been a promising research topic for building better and more reliable data-driven models. In particular, it is known that multimodal spectral imaging can improve the analytical capabilities of standalone spectroscopy techniques through fusion, hyphenation, or knowledge distillation techniques. In this manuscript, we focus on the latter, exploring how one can increase the performance of a Laser-induced Breakdown Spectroscopy system for mineral classification problems using additional spectral imaging techniques. Specifically, focusing on a scenario where Raman spectroscopy delivers accurate mineral classification performance, we show how to deploy a knowledge distillation pipeline where Raman spectroscopy may act as an autonomous supervisor for LIBS. For a case study concerning a challenging Li-bearing mineral identification of spodumene and petalite, our results demonstrate the advantages of this method in improving the performance of a single-technique system. LIBS trained with labels obtained by Raman presents an enhanced classification performance. Furthermore, leveraging the interpretability of the model deployed, the workflow opens opportunities for the deployment of assisted feature discovery pipelines, which may impact future academic and industrial applications.
2025
Authors
Preizal, J; Cosme, M; Pota, M; Caldas, P; Araujo, FM; Oliveira, R; Nogueira, R; Rego, GM;
Publication
29TH INTERNATIONAL CONFERENCE ON OPTICAL FIBER SENSORS
Abstract
In this paper we present results on the normalized temperature sensitivity of UV- and fs-induced fiber Bragg gratings in a singlemode fiber with similar to 4.7 mol% GeO2 and having an Ormocer coating. In the 1500-1600 nm wavelength range, the former shows an almost constant value of 6.165x10(-6) K-1, whilst the fs-induced present some variation not related with the strength of the grating but probably due to induced birefringence. The average value obtained was 6.191x10(-6) K-1 which is higher than the former. For the UV-induced gratings in the Corning SMF-28 fiber (3.67 mol% GeO2) the value obtained was 6.143x10(-6) K-1. The achieved values are compatible with the use of Corning 7980 silica-based cladding fiber. Preliminary results also show no measurable impact of the hydrogenation process or the strength of the grating on the normalized temperature sensitivity.
2025
Authors
Lorenzo Santini; Paulo Caldas; Luís C. Coelho;
Publication
29TH INTERNATIONAL CONFERENCE ON OPTICAL FIBER SENSORS
Abstract
A semi-distributed optical fiber bending extensometer system based on OTDR is proposed, consisting of N-loops designed to enable different maximum extension measurements and sensitivities. This system offers a low-cost solution for monitoring landslides and similar civil structures. Tests conducted at 1625 nm demonstrate that different series of sensors can be independently measured with elongation errors typically within +/- 0.25 cm across a range from 0 to 9 cm.
2025
Authors
Costa, MN; Cardoso, VHR; de Souza, MFC; Caldas, P; Giraldi, MTR; Frazao, O; Santos, J; Costa, JCWA;
Publication
29TH INTERNATIONAL CONFERENCE ON OPTICAL FIBER SENSORS
Abstract
A flexible wearable sensor utilizing a balloon-shaped interferometer structure, created from a bent standard single-mode fiber and a 3D-printed piece, was introduced and shown for respiratory monitoring. The interferometer is a compact, cost-effective, and easily fabricated sensor. The fiber's curvature causes interference between the core and cladding modes, which in turn results in the sensor operation. In the balloon-shaped curving section, light traversing the core partially escapes and interacts with the cladding. The preliminary results demonstrate an average displacement of 9.3 nm and the capability to evaluate breathing rate.
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