2021
Authors
Vasconcelos, H; Coelho, LCC; Matias, A; Saraiva, C; Jorge, PAS; de Almeida, JMMM;
Publication
BIOSENSORS-BASEL
Abstract
Biogenic amines (BAs) are well-known biomolecules, mostly for their toxic and carcinogenic effects. Commonly, they are used as an indicator of quality preservation in food and beverages since their presence in higher concentrations is associated with poor quality. With respect to BA's metabolic pathways, time plays a crucial factor in their formation. They are mainly formed by microbial decarboxylation of amino acids, which is closely related to food deterioration, therefore, making them unfit for human consumption. Pathogenic microorganisms grow in food without any noticeable change in odor, appearance, or taste, thus, they can reach toxic concentrations. The present review provides an overview of the most recent literature on BAs with special emphasis on food matrixes, including a description of the typical BA assay formats, along with its general structure, according to the biorecognition elements used (enzymes, nucleic acids, whole cells, and antibodies). The extensive and significant amount of research that has been done to the investigation of biorecognition elements, transducers, and their integration in biosensors, over the years has been reviewed.
2021
Authors
Vasconcelos, H; de Almeida, JMMM; Matias, A; Saraiva, C; Jorge, PAS; Coelho, LCC;
Publication
TRENDS IN FOOD SCIENCE & TECHNOLOGY
Abstract
Background: Biogenic amines (BAs) are compounds considered to be contaminants of foodstuff and are cause of poisoning. The main BAs found in foods are cadaverine, putrescine, tyramine, histamine, spermine and spermidine. The number of food poisoning cases associated with BAs in food has increased in the recent years reinforcing the need for early detection to ensure high levels of food quality and safety. Scope and approach: This review aims to provide a general approach to the different BAs detected in foods their concentrations and sample treatments. These compounds are found in varying concentrations in a wide variety of foods such as fish, meat, fruits, vegetables, cheese, wine, and beer. It also refers the different analytical techniques currently used for the detection of BAs, as well as the different treatments of the samples and innovations of the techniques currently used that allow greater sensitivity and speed of the analyzes and with obtaining detection limits lower and lower. Key findings and conclusions: BAs are present in a wide variety of foods and their concentration is highly influenced by the storage conditions of food products. BAs can be precursors of nitrosamines, which have been linked to carcinogenic and mutagenic activity. Several analytical techniques and sample treatments have been improved in the last few years for better and faster detection of BAs.
2021
Authors
Viveiros, D; de Almeida, JMMM; Coelho, L; Vasconcelos, H; Maia, JM; Amorim, VA; Jorge, PAS; Marques, PVS;
Publication
JOURNAL OF LIGHTWAVE TECHNOLOGY
Abstract
A detailed study of turn around point (TAP) long period fiber gratings (LPFGs) with coupling to the asymmetric cladding modes of a standard single-mode fiber (SMF-28e), fabricated by femtosecond (fs) laser direct writing was realized. The entire fabrication process, including the coating with different titanium dioxide (TiO2) film thicknesses of LPFGs and the corrections needed to achieve coated devices operating precisely in the TAP condition with coupling to the asymmetric cladding modes, was addressed. The significant fabrication details are also given, such as inscription periods, shape and localization of the refractive index modifications across the core. The fabrication process described allows the optimization of the LPFGs sensitivity in regards to the surrounding refractive index (SRI). Optimization of the writing parameters to obtain gratings working at the TAP for two different media surrounding the fiber (water and air) was achieved. It was demonstrated that for a grating period of 191.8 mu m, the LP1,12 mode exhibits a TAP at 1442.7 nm in air, and for a period of 192.5 mu m, the same mode exhibits a TAP at 1448.6 nm in water. The LPFGs operating at the TAP in air and water were coated with 10, 20, and 30 nm thin TiO2 film thicknesses and the spectral behavior characterized. The wavelength sensitivity to the surrounding refractive index (SRI) was assessed in the range between 1.3700 to 1.4120, and a maximum sensitivity of similar to 8051.4 nm/RIU was measured for the 192.5 mu m LPFG coated with a 30 nm thick TiO2 film.
2021
Authors
Vasconcelos, H; Matias, A; Jorge, P; Saraiva, C; Mendes, J; Araújo, J; Dias, B; Santos, P; Almeida, JMMM; Coelho, LCC;
Publication
Chemistry Proceedings
Abstract
2020
Authors
Viveiros, D; De Almeida, JMMM; Coelho, L; Vasconcelos, H; Maia, JM; Amorim, VA; Jorge, PAS; Marques, PVS;
Publication
Optics InfoBase Conference Papers
Abstract
The fabrication of Turn Around Point Long Period Fiber Grating in standard SMF-28e fibers through femtosecond laser direct writing is demonstrated and its sensing sensitivity is improved by coating the fiber with titanium dioxide through physical vapor deposition. © 2021 The Author(s).
2020
Authors
Viveiros, D; Vasconcelos, H; De Almeida, JMMM; Coelho, L; Amorim, VA; Maia, JM; Jorge, PAS; Marques, PVS;
Publication
Optics InfoBase Conference Papers
Abstract
Optical fiber Mach-Zehnder interferometers were fabricated by combining two TiO2 coated LPFGs fabricated through femtosecond laser direct writing. Results of its refractometric characterization are presented and compared with the single LPFGs sensors. Wavelength sensitivity of 1175 nm/RIU at 1.38 and spectral resolution of 2.2×10-5 were achieved. © 2021 The Author(s).
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