Abstract
Optical fiber optrodes are attractive sensing devices due to their ability to perform point measurement in remote locations. Mostly, they are oriented to biochemical sensing, quite often relying on fluorescent and spectroscopic techniques, but with the refractometric approach being also considered when the objective is high measurement performance, particularly when focusing on measurand resolution. In this work, we address this subject proposing and theoretically analyzing the characteristics of a fiber optic optrode relying on plasmonic interaction. The optrode structure is a fiber optic tapered tip layout incorporating a lateral bimetallic layer (silver + gold) and operating in reflection.

Abstract
Optical fiber sensors based on the phenomenon of plasmonic resonance can be interrogated applying different methods, the most common one being the spectral approach where the measurand information is derived from the reading of the wavelength resonance dip. In principle, a far better performance can be achieved considering the reading of the phase of the light at a specific wavelength located within the spectral plasmonic resonance. This approach is investigated in this work for fiber optic SPR sensors with overlays which are combinations of metallic and dielectric thin films, permitting not only to tune the wavelength of the SPR resonance but also the sensitivity associated with the phase interrogation of the sensors.

Abstract
Surface Plasmon Resonance (SPR) is the base for some of the most sensitive label free optical fiber biosensors. However, most solutions presented to date require the use of fragile fiber optic structure such as adiabatic tapers or side polished fibers. On the other hand, long-period fiber gratings (LPG) present themselves as an interesting solution to attain an evanescent wave refractive index sensor platform while preserving the optical fiber integrity. The combination of these two approaches constitute a powerful platform that can potentially reach the highest sensitivities as it was recently demonstrated by detailed theoretical study [1, 2]. In this work, a LPG-SPR platform is explored in different configurations (metal coating between two LPG - symmetric and asymmetric) operating in the telecom band (around 1550 nm). For this purpose LPGs with period of 396 mu m are combined with tailor made metallic thin films. In particular, the sensing regions were coated with 2 nm of chromium to improve the adhesion to the fiber and 16 nm of gold followed by a 100 nm thick layer of TiO2 dielectric material strategically chosen to attain plasmon resonance in the desired wavelength range. The obtained refractometric platforms were then validated as a biosensor. For this purpose the detection of thrombin using an aptamer based probe was used as a model system for protein detection. The surface of the sensing fibers were cleaned with isopropanol and dried with N-2 and then the aminated thrombin aptamer (5'-[NH2]-GGTTGGTGTGGTTGG-3') was immobilized by physisorption using Poly-L-Lysine (PLL) as cationic polymer. Preliminary results indicate the viability of the LPFG-SPR-APTAMER as a flexible platforms point of care diagnostic biosensors.

Abstract
A new type of fibre-optic refractive index sensor based on a long period fibre grating (LPFG) coated with a titanium dioxide (TiO2) thin film was demonstrated. The wavelength shift of the attenuation bands of this LPFG sensor to changes in the refractive index of the external media from 1.30 to 1.64 RIU was investigated. In order to optimize the sensor the TiO2 thin film thickness deposited around the LPFGs was varied from 10 to 80 nm. It was found that the TiO2 thin film increases the wavelength sensitivity of the LPFG to changes in the surrounding refractive index for values lower and higher than the cladding refractive index. As opposed to the bare LPFG it was shown the possibility to monitor refractive indices lower and higher than cladding refractive index tailoring the TiO2 thickness. An average wavelength sensitivity of 5250 nm/RIU was achieved in the range 1.444 to 1.456 RIU for a TiO2 thickness of 50 nm. In the region between 1.46 and 1.48 RIU the average sensitivity of about 825 nm/RIU was measured for a 40 nm thick film.

Abstract
Long period fiber gratings (LPFGs) were used to monitor the characteristics of copper (Cu) thin films when annealed in air atmosphere up to similar to 680 degrees C. The wavelength and the optical power shift of the resonant bands of the LPFGs when coated with the Cu thin films, were measured as a function of the annealing temperature, and were found to exhibit a different evolution comparing to a bare LPFGs. Thin films of Cu deposited on quartz (SiO2) substrates were annealed and analyzed by XRD, SEM/EDS and Raman spectroscopy, allowing to identify the formation of two distinct oxide phases at different temperatures, cuprous (Cu2O-cuprite) and cupric (CuO-tenorite) oxides, respectively. The observed features of the resonant bands of the LPFGs were found to be associated with the Cu oxide phase transitions, indicating the possibility of using LPFGs to monitor, in real time, the oxidation states of Cu thin films by following specific characteristics of the attenuation bands. In addition, LPFGs over coated with the two distinct oxidation phases of Cu were characterized for refractive index sensing in the range between 1.300 to 1.600, leading to the conclusion that the sensitivity to the refractive index of the surrounding medium of Cu coated LPFGs sensing systems can be temperature tuned.

Abstract
The recent burst of R&D activity in Plasmonics, associated with the possibility of materials nanostructuring which enables the access to metamaterials, has been strongly impacting many branches of optics such as imaging, data recording and sensing. This talk details the factors that turned the combination Plasmonics and Metamaterials a huge opportunity to optical sensing.© OSA 2014.