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Publications

Publications by CAP

2015

Radioisotope-based XRF instrumentation for determination of lead in paint: An assessment of the current accuracy and reliability of portable analyzers used in New York State

Authors
Guimarães, D; Cleaver, TM; Martin, SF; Parsons, PJ;

Publication
Analytical Methods

Abstract
Childhood lead poisoning remains a significant public health issue, especially in the United States, where the most common source of exposure is lead-based paint (LBP). X-Ray Fluorescence (XRF) analysis is still the most widely used method for detecting LBP in the field. Although portable XRF instrumentation based on excitation from a 57Co radioisotope has been used for more than 30 years, there have been few reports documenting its performance. Here we describe a study that was conducted by the New York State Department of Health's Wadsworth Center laboratory in response to concerns raised by field users of the RMD LPA-1 XRF analyzer (Protec Instrument Corp.) working across the state. The performance issues were investigated for ten field units: five reported as problematic based on user feedback, and 5 that were not. Accuracy was assessed against NIST SRM 2579 lead in paint, which was developed specifically for use with portable XRF analyzers. On average, the absolute bias found was within ±20% at the threshold value for LBP (1.0 mg cm-2) based on the NIST SRM 2579 data. Calibration blocks provided with each analyzer for quality assurance monitoring were evaluated using a different XRF analyzer (Niton XLT 3t 700s GOLDD) operated in painted products mode (µg cm-2). However, when the Niton XRF analyzer was checked against NIST SRM 2579, it was found to have a negative bias. That negative bias was easily corrected using a "calibration" curve with a quadratic fit to the data. NIST-corrected data obtained for the calibration blocks showed assigned values were within the manufacturer's stated tolerance range, albeit with a consistent positive bias. The root cause for 3 of the 5 problematic devices was likely incorrect positioning of the device. A low bias for a fourth device was likely caused by a deteriorated calibration block, and the fifth device, while just within the manufacturer's technical specifications, was the only one confirmed with a low bias. Increased operator training may resolve some of the issues reported in the field; on-going competency assessments may be warranted for this hand-held technology. © 2014 The Royal Society of Chemistry.

2015

Lithium batteries temperature and strain fiber monitoring

Authors
Nascimento, M; Novais, S; Leitao, C; Fatima Domingues, MF; Alberto, N; Antunes, P; Pinto, JL;

Publication
24TH INTERNATIONAL CONFERENCE ON OPTICAL FIBRE SENSORS

Abstract
Fiber Bragg grating sensors were attached to the surface of a rechargeable lithium battery in order to monitor its thermal and strain fluctuations through charge and different discharge C rates. During the discharge process above 1C, it were observed, a temperature and strain fluctuations of a 4.12 +/- 0.67 degrees C and 24.64 +/- 6.02 mu epsilon, respectively. In the regular charge process, a temperature and strain variation of 1.03 +/- 0.67 degrees C and 15.86 +/- 6.02 mu epsilon, were detected.

2015

On-field distributed first-order PMD measurement based on pOTDR and optical pulse width sweep

Authors
Franciscangelis, C; Floridia, C; Simões, GCCP; Schmmidt, F; Fruett, F;

Publication
Optics Express

Abstract

2015

Optimisation algorithms for OSNR measurement based on polarisation nulling

Authors
Feres, M; Floridia, C; Romero, M;

Publication
Electronics Letters

Abstract

2015

Quantitative and Qualitative Monitoring System for Switchgear With Full Electrical Isolation Using Fiber-Optic Technology

Authors
Rosolem, JB; Bassan, FR; Penze, RS; Floridia, C; Leonardi, AA; Pereira, FR; Nascimento, CAM;

Publication
IEEE Transactions on Power Delivery

Abstract

2015

Optical fibre intrusion detection method based on Lefevre-loop and bidirectional polarisation optical time-domain reflectometer-C technique

Authors
Franciscangelis, C; Floridia, C; Fruett, F;

Publication
The Journal of Engineering

Abstract

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