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Publicações

Publicações por Paulo Vicente Marques

2012

Determination of Microcystin-LR in waters in the subnanomolar range by sol-gel imprinted polymers on solid contact electrodes

Autores
Queiros, RB; Noronha, JP; Marques, PVS; Fernandes, JS; Sales, MGF;

Publicação
ANALYST

Abstract
The present work reports new sensors for the direct determination of Microcystin-LR (MC-LR) in environmental waters. Both selective membrane and solid contact were optimized to ensure suitable analytical features in potentiometric transduction. The sensing layer consisted of Imprinted Sol-Gel (ISG) materials capable of establishing surface interactions with MC-LR. Non-Imprinted Sol-Gel (NISG) membranes were used as negative control. The effects of an ionic lipophilic additive, time of sol-gel polymerization, time of extraction of MC-LR from the sensitive layer, and pH were also studied. The solid contact was made of carbon, aluminium, titanium, copper or nickel/chromium alloys (80 : 20 or 90 : 10). The best ISG sensor had a carbon solid contact and displayed average slopes of 211.3 mV per decade, with detection limits of 7.3 x 10(-10) M, corresponding to 0.75 mu g L-1. It showed linear responses in the range of 7.7 x 10(-10) to 1.9 x 10(-9) M of MC-LR (corresponding to 0.77-2.00 mu g L-1), thus including the limiting value for MC-LR in waters (1.0 mu g L-1). The potentiometric-selectivity coefficients were assessed by the matched potential method for ionic species regularly found in waters up to their limiting levels. Chloride (Cl-) showed limited interference while aluminium (Al3+), ammonium (NH4+), magnesium (Mg2+), manganese (Mn2+), sodium (Na+), and sulfate (SO42-) were unable to cause the required potential change. Spiked solutions were tested with the proposed sensor. The relative errors and standard deviation obtained confirmed the accuracy and precision of the method. It also offered the advantages of low cost, portability, easy operation and suitability for adaptation to flow methods.

2005

Photosensitive materials for integrated optic applications

Autores
Marques, PVS; Moreira, PJ; Alexandre, D; Melo, M; Schmidt, TEA; Muenzner, R; Leite, AMP; Aitchison, JS;

Publicação
FIBER AND INTEGRATED OPTICS

Abstract
This article presents results of device fabrication using UV processing of materials and integrated optic components produced by flame hydrolysis deposition and hybrid sol-gel technology. Photosensitive materials were employed in the fabrication of channel waveguides and channel photo-imprinted waveguides incorporating Bragg gratings through single and double-step exposure.

2005

Refractive index sensing with long-period grating fabricated in biconical tapered fibre

Autores
Allsop, T; Floreani, F; Jedrzejewski, K; Marques, P; Romero, R; Webb, D; Bennion, I;

Publicação
Electronics Letters

Abstract
A single long-period fibre grating was written in a biconical fibre taper made from standard communications step-index optical fibre, resulting in an interferometric fibre sensor device that provided a resolution of 1 × 10-4 for refractive indices in the range of 1.30 to 1.34, suggesting that these devices may be suitable for use with aqueous solutions. © IEE 2005.

2010

Low-cost optical components based on organic-inorganic hybrids produced using direct UV writing technique

Autores
Ferreira, RAS; Vicente, C; Xavier, LR; Fernandes, V; Carlos, LD; Andre, PS; Pecoraro, E; De Zea Bermudez, V; Monteiro, P; Marques, PVS;

Publicação
2010 12th International Conference on Transparent Optical Networks, ICTON 2010

Abstract
In this paper, direct UV-laser writing was used to produce channel waveguides and diffraction gratings on thin films of siliceous-based organic-inorganic hybrid materials. The optical quality of the films surface was studied by light scattering measurements. The produced Y-power splitters, optical filters and Fabry-Perot cavities were experimentally characterized for propagation in the near infrared spectral region. © 2010 IEEE.

2002

Simultaneous UV direct writing of channel waveguides and Bragg gratings in germanium-doped planar silica

Autores
Marques, PVS; Bonar, JR; Leite, AMP; Aitchison, JS;

Publicação
IEEE JOURNAL OF SELECTED TOPICS IN QUANTUM ELECTRONICS

Abstract
Channel waveguides incorporating photo-imprinted Bragg gratings were produced in germano-borosilicate glass layers fabricated by flame hydrolysis deposition, through single-and double-step exposure direct writing processes with UV laser irradiation. To our knowledge, this is the first time that UV exposure has been used to simultaneously realize both waveguiding and spectral selectivity functions.

2011

Integrated optical temporal Fourier transformer based on a chirped Bragg grating waveguide

Autores
Dolgaleva, K; Malacarne, A; Tannouri, P; Fernandes, LA; Grenier, JR; Aitchison, JS; Azana, J; Morandotti, R; Herman, PR; Marques, PVS;

Publicação
OPTICS LETTERS

Abstract
We experimentally demonstrate the first integrated temporal Fourier transformer based on a linearly chirped Bragg grating waveguide written in silica glass with a femtosecond laser. The operation is based on mapping the energy spectrum of the input optical signal to the output temporal waveform by making use of first-order chromatic dispersion. The device operates in reflection, has a bandwidth of 10 nm, and can be used for incident temporal waveforms as long as 20 ps. Experimental results, obtained through both temporal oscilloscope traces and Fourier transform spectral interferometry, display a successful Fourier transformation of in-phase and out-of-phase pairs of input optical pulses, and demonstrate the correct functionality of the device for both amplitude and phase of the temporal output. (C) 2011 Optical Society of America

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