Cookies
O website necessita de alguns cookies e outros recursos semelhantes para funcionar. Caso o permita, o INESC TEC irá utilizar cookies para recolher dados sobre as suas visitas, contribuindo, assim, para estatísticas agregadas que permitem melhorar o nosso serviço. Ver mais
Aceitar Rejeitar
  • Menu
Publicações

Publicações por Luís Carlos Coelho

2023

Refractometric sensitivity of Bloch surface waves : perturbation theory calculation and experimental validation

Autores
Dias, BS; De Almeida, JMMM; Coelho, LCC;

Publicação
OPTICS LETTERS

Abstract
The sensitivity of one-dimensional Bloch surface wave (BSW) sensors to external refractive index variations using Kretschmann's configuration is calculated analytically by employing first-order perturbation theory for both TE and TM modes. This approach is then validated by com- parison with both transfer matrix method simulations and experimental results for a chosen photonic crystal structure. Experimental sensitivities of (8.4 +/- 0.2)x102 and (8.4 +/- 0.4)x102 nm/RIU were obtained for the TE and TM BSW modes, corresponding to errors of 0.02% and 4%, respectively, when comparing with the perturbation the- ory approach. These results provide interesting insights into photonic crystal design for Bloch surface wave sensing by casting light into the important parameters related with sen- sor performance.(c) 2023 Optica Publishing Group

2023

Measuring Water Vapor Sorption Hysteresis of Cement Paste through an Optical Fiber Sensor

Autores
da Silva, PM; Coelho, LCC; de Almeida, JMMM;

Publicação
CHEMOSENSORS

Abstract
Water vapor sorption is a powerful tool for the analysis of cement paste, one of the most used substances by mankind. The monitoring of cementitious materials is fundamental for the improvement of infrastructure resilience, which has a deep impact on the economy, the environment, and on society. In this work, a multimode fiber was embedded in cement paste for real-time monitoring of cement paste water vapor sorption. Changes in the reflected light intensity due to the build-up of water in the cement paste's pores were exploited for this purpose. The sample was 7-day moist cured, and the relative humidity was controlled between 8.9% and 97.6%. Reflected light intensity was converted into a specific surface area of cement paste (133 m(2)/g) and thickness of water through the Brunauer-Emmett-Teller (BET) method and into a pore size distribution through the Barret-Joyner-Halenda (BJH) method. The results achieved through reflected light intensity agree with those found in the literature, validating the usage of this setup for the monitoring of water vapor sorption, breaking away from standard gravimetric measurements.

2023

Spectral Analysis Methods for Improved Resolution and Sensitivity: Enhancing SPR and LSPR Optical Fiber Sensing

Autores
Dos Santos, PSS; Mendes, JP; Dias, B; Perez-Juste, J; De Almeida, JMMM; Pastoriza-Santos, I; Coelho, LCC;

Publicação
SENSORS

Abstract
Biochemical-chemical sensing with plasmonic sensors is widely performed by tracking the responses of surface plasmonic resonance peaks to changes in the medium. Interestingly, consistent sensitivity and resolution improvements have been demonstrated for gold nanoparticles by analyzing other spectral features, such as spectral inflection points or peak curvatures. Nevertheless, such studies were only conducted on planar platforms and were restricted to gold nanoparticles. In this work, such methodologies are explored and expanded to plasmonic optical fibers. Thus, we study-experimentally and theoretically-the optical responses of optical fiber-doped gold or silver nanospheres and optical fibers coated with continuous gold or silver thin films. Both experimental and numerical results are analyzed with differentiation methods, using total variation regularization to effectively minimize noise amplification propagation. Consistent resolution improvements of up to 2.2x for both types of plasmonic fibers are found, demonstrating that deploying such analysis with any plasmonic optical fiber sensors can lead to sensing resolution improvements.

2020

Optical fiber probes for trapping and backscattered signal analysis of sub-mm particles

Autores
Rodrigues, SM; Paiva, JS; Silva, FM; Coelho, L; Marques, PVS; Cunha, JPS; Jorge, PAS;

Publicação
Optics InfoBase Conference Papers

Abstract
Optical tweezers based on metallic-coated tapered optical fibers with an aperture at the apex are fabricated and their sensing ability is tested. Preliminary results show robustness in differentiating between a trapped and no trapped state. © 2021 The Author(s).

2023

Compact biosensor system for the quantification of hydrogen peroxide in milk

Autores
Vasconcelos, H; Matias, A; Mendes, J; Araujo, J; Dias, B; Jorge, PAS; Saraiva, C; de Almeida, JMMM; Coelho, LCC;

Publicação
TALANTA

Abstract
Hydrogen peroxide is usually added to products to delay the development of microorganisms mainly in milk, hence increasing its stability over time, however the side effects can become devastating to human health.A technique is presented consisting of detecting hydrogen peroxide as an adulterant in milk through a sensor where pretreatment of the sample is not necessary, using a single use membrane. The detection of hydrogen peroxide in fresh-raw, whole, semi-skimmed and skimmed milk was performed using a luminol chem-iluminescence reaction.For hydrogen peroxide water solutions, a linear response was attained from 1.0 x 10-4 to 9.0 x 10-3 %w/w and an LOD (limit of detection) of 3.0 x 10-5 %w/w was determined. An R-squared value of 0.97 and a relative standard deviation lower than 10%, were achieved.Hydrogen peroxide concentration as low as 1.0 x 10-3 %w/w was measured for fresh-raw, skim and whole milk and for semi-skimmed milk, as low as 2.0 x 10-3 %w/w.The methodology presented, as long as our knowledge, is original, rapid, ecological and inexpensive. In regard of the sensitivity obtained, the methodology has great possibility to be applied in the detection of hydrogen peroxide in several areas. It is envisaged monitoring of food quality, agriculture systems and environment pollution.

2026

Tamm Plasmon Resonance-Enhanced Infrared Sensor for Hydrogen Detection: Numerical and Experimental Insights

Autores
Almeida, AS; Carvalho, PM; Santos, D; Pastoriza Santos, I; de Almeida, MMM; Coelho, CC;

Publicação
ACS Sensors

Abstract
Hydrogen (H2) detection has become extremely important in recent years due to the increasing need for sustainable alternative energy sources. In this field, optical sensors can contribute significantly due to remote interrogation capabilities and the absence of ignition sources. Among the different H2 optical sensors, plasmonic sensors appear to be a very sensitive technology; however, they require expensive plasmonic materials like gold or silver, which, together with a palladium-sensitive layer, can increase the sensor cost. In addition, plasmonic bands are usually outside the ideal infrared range for remote interrogation, between 1500 and 1600 nm. This work presents a polymer-protected Tamm Plasmon Resonance (TPR) sensor with a well-defined resonance band at 1572 nm composed of SiO2, TiO2 layers, and palladium as a sensitive layer. This architecture can reduce the production cost of sensing structures, replacing plasmonic films with dielectric materials, while offering improved resonance definition at longer wavelengths. First, numerical calculations were carried out using the Transfer-Matrix Method to study the impact of the thickness of each layer, incidence angle, and light polarization on the resonance band wavelength and H2 sensitivity. The optimized structure was then fabricated, exhibiting a wavelength shift of 9.5 nm to 4 vol % of H2, a response time of 30 s, and no cross-sensitivity to methane or ammonia. The sensor also demonstrated high stability and resistance to environmental degradation up to eight days. These results emphasize the advantages of TPR structures for gas sensing in the infrared spectral range, opening new avenues for remote plasmonic sensing. © 2026 The Authors. Published by American Chemical Society

  • 30
  • 30