Abstract
A scheme for the simultaneous determination of temperature and analyte concentration for application in luminescence-based chemical sensors is proposed. This scheme is applied to an optical oxygen sensor, which is based on the quenching of the fluorescence of a ruthenium complex. Temperature measurement is performed using the excitation radiation and an absorption long-pass filter. Preliminary results are presented that show the viability of an oxygen measurement that is independent of temperature and optical power level. The possibility of self-referenced temperature measurements with semiconductor nanoparticles is also investigated. In order to optimize the sensor design, several different optical fiber probe geometries for oxygen sensing are tested and compared, including different methods of coupling radiation into the optical fiber system. Polyvinyl alcohol (PVA) and polyacrylamide membranes are tested as supports for sensor immobilization in fiber-optical pH sensing devices in aqueous solution. Some results are presented that show the feasibility of using fiber-optical pH indicators for remote monitoring.

Abstract
An optical fiber sensing system, for monitoring oxygen aiming in vivo nuclear magnetic resonance (NMR) applications is presented. Oxygen detection is based on the dynamic quenching of the fluorescence of a ruthenium complex trapped in the porous structure of a sol-gel silica film. Oxygen concentration is determined by phase-modulation fluorometry. Preliminary results concerning the characterization of doped sol-gel thin films deposited by dip coating in glass slides and in optical fiber probes are presented. Four different probe configurations are tested and compared. Best results are obtained with a fiber taper configuration which shows reproducibility and best excitation efficiency. This structure is fully characterized and some considerations regarding optimal fiber optical sensing probes for 02 detection are addressed.

Abstract
An optical fiber sensor for the measurement of oxygen in gaseous environments, which is based on the quenching of the fluorescence of a ruthenium complex, is presented. The sensing chemistry is immobilized in a sol-gel based solid matrix that is coated on a tapered optical fiber probe. Oxygen measurement is performed both by phase and fluorescence intensity spectroscopy. Experimental results show that the fluorescence intensity and the lifetime depend both on oxygen and temperature. A scheme for simultaneous determination of the temperature and the oxygen concentration is proposed. Temperature measurement is performed using the excitation radiation and an absorption long pass filter. Preliminary results are presented which show a temperature measurement independent of oxygen and of optical power level.

Abstract
Extreme Learning Machines (ELMs) are a versatile Machine Learning (ML) algorithm that features as the main advantage the possibility of a seamless implementation with physical systems. Yet, despite the success of the physical implementations of ELMs, there is still a lack of fundamental understanding in regard to their optical implementations. In this context, this work makes use of an optical complex media and wavefront shaping techniques to implement a versatile optical ELM playground to gain a deeper insight into these machines. In particular, we present experimental evidences on the correlation between the effective dimensionality of the hidden space and its generalization capability, thus bringing the inner workings of optical ELMs under a new light and opening paths toward future technological implementations of similar principles.