2023
Autores
Soares, L; Perez Herrera, RA; Novais, S; Ferreira, A; Silva, S; Frazao, O;
Publicação
PHOTONICS
Abstract
Process Analytical Technology (PAT) has been increasingly used in the pharmaceutical industry to monitor essential parameters in real-time during pharmaceutical processes. The concentration of Active Pharmaceutical Ingredients (APIs), such as paracetamol, is one of these parameters, and controlling its variations allows for optimization of the production process. In this study, a refractometric sensor, implemented by an interrogation system based on an Erbium-Doped Fiber Ring Cavity (EDFRC), was presented and experimentally demonstrated. The Cavity Ring proposed included a 1 x 3 coupler. One port of the coupler was used to increase the optical power of the system through a Fiber Bragg Grating (FBG), and the other two ports were used as sensing head and reference. The sensor detected variations of paracetamol concentration with a sensitivity of [(-1.00 +/- 0.05) x 10(-3)] nW/(g/kg) and a resolution of 5.53 g/kg. The results demonstrate the potential of this technology as a possible non-invasive PAT tool.
2023
Autores
Robalinho, P; Soares, B; Lobo, A; Silva, S; Frazao, O;
Publicação
SENSORS
Abstract
In this paper, a different Fiber Loop Mirror (FLM) configuration with two circulators is presented. This configuration is demonstrated and characterized for sensing applications. This new design concept was used for strain and torsion discrimination. For strain measurement, the interference fringe displacement has a sensitivity of (0.576 +/- 0.009) pm.mu epsilon(-1). When the FFT (Fast Fourier Transformer) is calculated and the frequency shift and signal amplitude are monitored, the sensitivities are (-2.1 +/- 0.3) x 10(-4) nm(-1) mu epsilon(-1) and (4.9 +/- 0.3) x 10(-7) mu epsilon(-1), respectively. For the characterization in torsion, an FFT peaks variation of (-2.177 +/- 0.002) x 10(-12) nm(-1)/degrees and an amplitude variation of (1.02 +/- 0.06) x 10(-3)/degrees are achieved. This configuration allows the use of a wide range of fiber lengths and with different refractive indices for controlling the free spectral range (FSR) and achieving refractive index differences, i.e., birefringence, higher than 10(-2), which is essential for the development of high sensitivity physical parameter sensors, such as operating on the Vernier effect. Furthermore, this FLM configuration allows the system to be balanced, which is not possible with traditional FLMs.
2023
Autores
Rego, G;
Publicação
SENSORS
Abstract
This paper presents a thorough analysis on the temperature dependence of the thermo-optic coefficient, dn/dT, of four bulk annealed pure-silica glass samples (type I-natural quartz: Infrasil 301; type II-quartz crystal powder: Heraeus Homosil; type III-synthetic vitreous silica: Corning 7980 and Suprasil 3001) from room temperature down to 0 K. The three/four term temperature dependent Sellmeier equations and respective coefficients were considered, which results from fitting to the raw data obtained by Leviton et al. The thermo-optic coefficient was extrapolated down to zero Kelvin. We have obtained dn/dT values ranging from 8.16 x 10(-6) up to 8.53 x 10(-6) for the four samples at 293 K and for a wavelength of 1.55 & mu;m. For the Corning 7980 SiO2 glass, the thermo-optic coefficient decreases monotonically, from 8.74 x 10(-6) down to 8.16 x 10(-6), from the visible range up to the third telecommunication window, being almost constant above 1.3 & mu;m. The Ghosh's model was revisited, and it was concluded that the thermal expansion coefficient only accounts for about 2% of the thermo-optic coefficient, and we have obtained an expression for the temperature behavior of the silica excitonic bandgap. Wemple's model was also analyzed where we have also considered the material dispersion in order to determine the coefficients and respective temperature dependences. The limitations of this model were also discussed.
2023
Autores
Silva, D; Ferreira, T; Moreira, FC; Rosa, CC; Guerreiro, A; Silva, NA;
Publicação
JOURNAL OF THE EUROPEAN OPTICAL SOCIETY-RAPID PUBLICATIONS
Abstract
Extreme Learning Machines (ELMs) are a versatile Machine Learning (ML) algorithm that features as the main advantage the possibility of a seamless implementation with physical systems. Yet, despite the success of the physical implementations of ELMs, there is still a lack of fundamental understanding in regard to their optical implementations. In this context, this work makes use of an optical complex media and wavefront shaping techniques to implement a versatile optical ELM playground to gain a deeper insight into these machines. In particular, we present experimental evidences on the correlation between the effective dimensionality of the hidden space and its generalization capability, thus bringing the inner workings of optical ELMs under a new light and opening paths toward future technological implementations of similar principles.
2023
Autores
Silva, SO;
Publicação
Proceedings of the 11th International Conference on Photonics, Optics and Laser Technology, PHOTOPTICS 2023, Lisbon, Portugal, February 16-18, 2023.
Abstract
2023
Autores
Perez Herrera, RA; Soares, L; Novais, S; Frazão, O; Silva, S;
Publicação
Proceedings of SPIE - The International Society for Optical Engineering
Abstract
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