2010
Autores
Lima, SEU; Frazao, O; Farias, RG; Araujo, FM; Ferreira, LA; Miranda, V; Santos, JL;
Publicação
MICROWAVE AND OPTICAL TECHNOLOGY LETTERS
Abstract
This article reports the development of two sensing head configurations based on extrinsic and intrinsic fiber Fabry-Perot interferometers for the detection of incipient faults in oil-filled power transformers. The performances of the sensing heads are characterized and compared with the situations where it operates in air, water, and oil and promising results are obtained, which will allow the industrial development of practical solutions. (C) 2010 Wiley Periodicals, Inc. Microwave Opt Technol Lett 52: 1129-1134, 2010; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/mop.25139
2010
Autores
Lima, SEU; Frazao, O; Farias, RG; Araujo, FM; Ferreira, LA; Miranda, V; Santos, JL;
Publicação
FOURTH EUROPEAN WORKSHOP ON OPTICAL FIBRE SENSORS
Abstract
Acoustic emission monitoring is often used in the diagnosis of electrical and mechanical incipient faults in high voltage apparatus. Partial discharges are a major source of insulation failure in power transformers and the differentiation from other sources of acoustic emissions is of the utmost importance. Also, it is important to give an indication of the PD source location in order to obtain a useful diagnosis. This paper reports the developments in partial discharges source location through the associated acoustic emissions using three different algorithms.
2010
Autores
Lima, SEU; Frazao, O; Farias, RG; Araujo, FM; Ferreira, LA; Miranda, V; Santos, JL;
Publicação
FOURTH EUROPEAN WORKSHOP ON OPTICAL FIBRE SENSORS
Abstract
Partial discharges are a major source of insulation failure in electric power transformers. Their detection can be achieved through the associated acoustic emissions, and this work reports on the investigation of a fibre laser sensor based on a phase-shifted chirped fibre grating for acoustic emission detection in the power transformer environment. The performance of the sensing head is characterized and compared for different surrounding media: air, water and oil.
2010
Autores
Goncalves, H; Jorge, PAS; Fernandes, JRA; Esteves da Silva, JCGE;
Publicação
SENSORS AND ACTUATORS B-CHEMICAL
Abstract
The synthesis of carbon nanoparticles obtained by direct laser ablation [UV pulsed laser irradiation (248 nm, KrF)] of carbon targets immersed in water is described. Laser ablation features were optimized to produce carbon nanoparticles with dimensions up to about 100 nm. After functionalization with NH2-polyethylene-glycol (PEG(200)) and N-acetyl-L-cysteine (NAC) the carbon nanoparticles become fluorescent with excitation and emission wavelengths at 340 and 450 nm, respectively. The fluorescence decay time was complex and a three-component decay time model originated a good fit (chi = 1.09) with the following lifetimes: tau(1) = 0.35 ns; tau(2) = 1.8 ns; and tau(3) = 4.39 ns. The fluorescence of the carbon dots is sensitive to pH with an apparent PKa = 4.2. The carbon dots were characterized by H-1 NMR and HSQC and the results show an interaction between PEG(200) and the carbon surface as well as a dependence of the chemical shift with the reaction time. The fluorescence intensity of the nanoparticles is quenched by the presence of Hg(II) and Cu(II) ions with a Stern-Volmer constant (pH = 6.8) of 1.3 x 10(5) and 5.6 x 10(4) M-1, respectively. As such the synthesis and application of a novel biocompatible nanosensor for measuring Hg(II) is presented.
2010
Autores
Palmeira, J; Lopes, L; Silva, AJ; Jorge, PAS; Oliva, A;
Publicação
Diffusion and Defect Data Pt.B: Solid State Phenomena
Abstract
In the recent years, sol-gel films have been intensively used in optical sensors configurations. Due to its hydrophobic nature, ormosil films have been reported to be a promising supporting matrix for oxygen sensing dyes for measurements in aqueous media. In this work, the impact of the sol-gel host fabrication parameters in the characteristics of the resulting oxygen sensing membranes is thoroughly evaluated. Different combinations of organic-inorganic precursors, with different aging times, were tested as oxygen sensors. All the solution were doped with ruthenium complex Ru(II)-tris(4,7-diphenyl-1,10- phenanthroline) to introduce oxygen sensitivity. Thin films were produced by dip coating of glass slides. The oxygen sensitive films were tested in aqueous phase in equilibrium with different oxygen gas compositions, using a phase-modulation technique. Sensor performance parameters such as Stern-Volmer constant, quenching efficiency and lifetime response are reported. The data obtained clearly indicates that increased aging times and longer organic groups produce sensors with the highest sensitivity to dissolved oxygen. From all sol-gel films produced, the BTEOS:TEOS (1:1) mixture is the most promising for sensor construction. © (2010) Trans Tech Publications.
2010
Autores
Duarte, AJ; Rocha, C; Silveira, F; Aguilar, GG; Jorge, PAS; Leitao, JMM; Algarra, M; Esteves da Silva, JCGE;
Publicação
ANALYTICAL LETTERS
Abstract
Silica based nanostructured composite materials doped with luminol and cobalt(II) ion were synthesized and characterized, resulting in a highly chemiluminescent material in the presence of hydrogen peroxide. A detection system with the CL light guided from the reaction tube to the photomultiplier tube using a one millimeter glass optical fiber was developed and assessed. A linear response was observed using a semi-logarithm calibration between 50-2000M hydrogen peroxide with 1M as the limit of detection.
The access to the final selection minute is only available to applicants.
Please check the confirmation e-mail of your application to obtain the access code.