2012
Autores
Pontes, MJ; Segatto, MEV; Barbero, APL; Rocco Giraldi, MTM; Rocha, AM; Neto, B; Costa, JCW; Martinez, MAG; Frazao, O; Baptista, JM; Salgado, H; Teixeira, ALJ; Andre, PS;
Publicação
MICROWAVE AND OPTICAL TECHNOLOGY LETTERS
Abstract
This article analyzes experimentally the limitations observed in a 45 km Raman amplified 4 x 40 Gb/s transmission system operating under multiple pump and single high pump power configurations. A signal-to-noise ratio of 19.2 dB, an extinction ratio of 10.4 dB and a jitter of 1097 fs are achieved for moderate pump powers and higher order stimulated Brillouin scattering lines give rise to system degradation for pump power levels more than 0.5 W. (C) 2012 Wiley Periodicals, Inc. Microwave Opt Technol Lett 54:14031407, 2012; View this article online at wileyonlinelibrary.com. DOI 10.1002/mop.26827
2012
Autores
Custodio, LM; Sousa, CT; Ventura, J; Teixeira, JM; Marques, PVS; Araujo, JP;
Publicação
PHYSICAL REVIEW B
Abstract
The Bruggeman effective medium is used to study the transition to hyperbolic dispersion of visible light in thin-film metal-dielectric composite metamaterial of varying mixing proportion. This transition is experimentally demonstrated by the detection of the swap between the refracted birefringence components in fabricated composites of silver nanowires embedded in anodic aluminium oxide. Three refraction regimes are observed in a single composite using excitation radiation on both sides of the transition.
2012
Autores
Queiros, RB; Noronha, JP; Marques, PVS; Sales, MGF;
Publicação
26TH EUROPEAN CONFERENCE ON SOLID-STATE TRANSDUCERS, EUROSENSOR 2012
Abstract
Microcystin-LR (MC-LR) is a dangerous toxin found in environmental waters, quantified by high performance liquid chromatography and/or enzyme-linked immunosorbent assays. Quick, low cost and on-site analysis is thus required to ensure human safety and wide screening programs. This work proposes label-free potentiometric sensors made of solid-contact electrodes coated with a surface imprinted polymer on the surface of Multi-Walled Carbon NanoTubes (CNTs) incorporated in a polyvinyl chloride membrane. The imprinting effect was checked by using non-imprinted materials. The MC-LR sensitive sensors were evaluated, characterized and applied successfully in spiked environmental waters. The presented method offered the advantages of low cost, portability, easy operation and suitability for adaptation to flow methods. (C) 2012 Elsevier Ltd....Selection and/or peer-review under responsibility of the Symposium Cracoviense Sp. z.o.o.
2012
Autores
Queiros, RB; Noronha, JP; Marques, PVS; Fernandes, JS; Sales, MGF;
Publicação
ANALYST
Abstract
The present work reports new sensors for the direct determination of Microcystin-LR (MC-LR) in environmental waters. Both selective membrane and solid contact were optimized to ensure suitable analytical features in potentiometric transduction. The sensing layer consisted of Imprinted Sol-Gel (ISG) materials capable of establishing surface interactions with MC-LR. Non-Imprinted Sol-Gel (NISG) membranes were used as negative control. The effects of an ionic lipophilic additive, time of sol-gel polymerization, time of extraction of MC-LR from the sensitive layer, and pH were also studied. The solid contact was made of carbon, aluminium, titanium, copper or nickel/chromium alloys (80 : 20 or 90 : 10). The best ISG sensor had a carbon solid contact and displayed average slopes of 211.3 mV per decade, with detection limits of 7.3 x 10(-10) M, corresponding to 0.75 mu g L-1. It showed linear responses in the range of 7.7 x 10(-10) to 1.9 x 10(-9) M of MC-LR (corresponding to 0.77-2.00 mu g L-1), thus including the limiting value for MC-LR in waters (1.0 mu g L-1). The potentiometric-selectivity coefficients were assessed by the matched potential method for ionic species regularly found in waters up to their limiting levels. Chloride (Cl-) showed limited interference while aluminium (Al3+), ammonium (NH4+), magnesium (Mg2+), manganese (Mn2+), sodium (Na+), and sulfate (SO42-) were unable to cause the required potential change. Spiked solutions were tested with the proposed sensor. The relative errors and standard deviation obtained confirmed the accuracy and precision of the method. It also offered the advantages of low cost, portability, easy operation and suitability for adaptation to flow methods.
2012
Autores
Grenier, JR; Fernandes, LA; Aitchison, JS; Marques, PVS; Herman, PR;
Publicação
OPTICS LETTERS
Abstract
Phase-shifted Bragg grating waveguides (PSBGWs) were formed in bulk fused silica glass by femtosecond laser direct writing to produce narrowband (22 +/- 3) pm filters at 1550 nm. Tunable p and other phase shifts generated narrow passbands in controlled positions of the Bragg stopband, while the accurate placement of multiple cascaded phase-shift regions yielded a rectangular-shaped bandpass filter. A waveguide birefringence of (7.5 +/- 0.3) x 10(-5) is inferred from the polarization-induced spectral shifting of the PSBGW narrowband filters. (C) 2012 Optical Society of America
2012
Autores
Fernandes, LA; Grenier, JR; Herman, PR; Aitchison, JS; Marques, PVS;
Publicação
OPTICS EXPRESS
Abstract
Femtosecond laser exposure produces form and stress birefringence in glasses, mainly controlled by laser polarization and pulse energy, which leads to challenges in certain applications where polarization mode dispersion or birefringence splitting is critical for the desired responses from optical devices. In this paper, parallel laser modification tracks with different geometries were applied to preferentially stress the laser-written waveguides and explore the possibility of tuning the waveguide birefringence in devices fabricated in bulk fused silica glass. Polarization splitting in Bragg grating waveguides showed the laser modification tracks to controllably add or subtract stress to the pre-existing waveguide birefringence, demonstrating independence from the nanograting induced form birefringence and the contributions from material stress. Stressing bars are shown that offer tunable birefringence in the range from similar to 0 up to 4.35 x 10(-4), possibly enabling great flexibility in designing polarization dependent devices, as well as making polarization independent devices. (C) 2012 Optical Society of America
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