Abstract
This paper introduces a new variable structure controller designed for depth control of an autonomous underwater sensor platform equipped with a variable buoyancy module. To that end, the prototype linear model is presented, and a finite element-based method is used to estimate one of its parameters, the hull deformation due to pressure. To manage potential internal disturbances like hull deformation or external disturbances like weight changes, a disturbance observer is developed. An analysis of the observer steady-state estimation error in relation to input disturbances and system parameter uncertainties is developed. The locations of the observer poles according to its parameters are also identified. The variable structure controller is developed, keeping energy savings in mind. The proposed controller engages when system dynamics are unfavorable, causing the vehicle to deviate from the desired reference, and disengages when dynamics are favorable, guiding the vehicle toward the target reference. A detailed analysis determines the necessary switching control actions to ensure the system reaches the desired reference. Finally, simulations are run to compare the proposed controller's performance with that of PID-based controllers recently developed in the literature, assessing dynamic response and energy consumption under various operating conditions. Both the VBM- and propeller-actuated vehicles were evaluated. The results demonstrate that the proposed controller achieves an average energy consumption reduction of 22% compared to the next most efficient PID-based controller for the VBM-actuated vehicle, though with some impact on control performance.

Abstract
Participatory processes are an essential aspect of collaborative planning and decision-making processes, but designing such processes effectively can be quite challenging. This work departs from the assumptions that in sustainable urban mobility planning, the functional urban area needs to be considered, and that citizen engagement is often enacted at the neighborhood level. Under these assumptions, we have examined the experiences of 6 metropolitan cases (Bologna, Nantes, Manchester, Montreal, Christchurch, and Santiago de Chile) and draw insights from their experiences. We conclude this work with some general reflections on the importance of systemic approaches to effectively plan for sustainable transitions in urban mobility.

Abstract
Precision spraying in agriculture is crucial for optimizing the application of pesticides while minimizing environmental impact. Despite significant advancements in control models for spraying systems, predictive control algorithms were not used. This paper addresses this gap by proposing a real-time control framework that integrates predictive control strategies to ensure consistent pressure output in a trailer sprayer. Based on information from various sensors, the framework anticipates and adapts to dynamic environmental conditions, enhancing accuracy and sustainability in spraying practices. A methodology is developed to define a proportional valve model. Based on this valve model, the predictive control model optimizes valve movements to minimize errors between predicted and reference pressures, thereby improving spraying efficiency. This study demonstrates the viability of predictive control in improving precision spraying systems applicable to autonomous robots, encouraging future advances in agricultural spraying technologies.

Abstract
The manufacturing domain faces a challenge in making timely decisions due to the large amounts of data generated by digital technologies such as Internet-of-Things, Artificial Intelligence (AI), Digital Twin, and Big Data. By integrating recommendation systems is possible to support the decision-makers in handling large amounts of data by delivering personalised, accurate, and quality recommendations. One example is the SimQL recommendation model that incorporates AI algorithms with trust and similarity measures to enhance recommendation quality. This paper aims to analyse the sensitivity of the SimQL model's parameters, such as dataset conditions, trust and learning factors, and their impact on the final recommendation quality. A fuzzy logic approach is employed to evaluate the model and identify optimal operating conditions for the recommendation system. By implementing the findings of this study, manufacturers can improve the acceptance and adoption of the SimQL trustworthy recommendation system in this field.

Abstract
Road network studies attracted unprecedented and overwhelming interest in recent years due to the clear relationship between human existence and city evolution. Current studies cover many aspects of a road network, for example, road feature extraction from video/image data, road map generalisation, traffic simulation, optimisation of optimal route finding problems, and traffic state prediction. However, analysing road networks as a complex graph is a field to explore. This study presents comparative studies on the Porto, in Portugal, road network sections, mainly of Matosinhos, Paranhos, and Maia municipalities, regarding degree distributions, clustering coefficients, centrality measures, connected components, k-nearest neighbours, and shortest paths. Further insights into the networks took into account the community structures, page rank, and small-world analysis. The results show that the information exchange efficiency of Matosinhos is 0.8, which is 10 and 12.8% more significant than that of the Maia and Paranhos networks, respectively. Other findings stated are: (1) the studied road networks are very accessible and densely linked; (2) they are small-world in nature, with an average length of the shortest pathways between any two roads of 29.17 units, which as found in the scenario of the Maia road network; and (3) the most critical intersections of the studied network are 'Avenida da Boavista, 4100-119 Porto (latitude: 41.157944, longitude: - 8.629105)', and 'Autoestrada do Norte, Porto (latitude: 41.1687869, longitude: - 8.6400656)', based on the analysis of centrality measures.

Abstract
Molecularly imprinted polymers (MIPs) are biomimetic materials of great interest in the scientific and industrial fields for the development of innovative sensing strategies. Herein, we proposed a new sensing application by developing an electrochemical sensor using molecular imprinting (MI) technology for recognition of atrial natriuretic peptide (ANP) both as a free molecule in solution and attached to nanoparticle-based drug delivery systems (DDSs), aiming to provide fast and reliable information on the cell uptake of nanoparticles (NPs). As proof of concept, poly(lactic-co-glycolic acid) (PLGA) NPs were synthesized and used as nanocarriers for ischemic heart disease therapy were synthesized and then functionalized with ANP (named here as PLGANPs@ANP). The MIP receptor film was prepared by electrochemical polymerization of dopamine over the working area of a gold screen-printed electrode (AuSPE), using cyclic voltammetry (CV) technique. The construction of the ANP sensor was carefully optimized to enhance its performance, including the film thickness and the procedures for effective template extraction from the MIP matrix. The MIP biosensor presented a linear response against polymeric NPs (PLGA-NPs@ANP) concentration logarithm ranging from 4.0 mu g mL(-1) to 100 mu g mL(-1), with a sensitivity of - 0.0129 mA mL mu g(-1) decade(-1) and an LOD < 4.0 g mL(-1). Furthermore, the developed MIP receptor film was able to discriminate ANP-functionalized nanocarriers from non-functionalized NPs.