Abstract
A novel technique based on multiple amplitude wavelength modulation spectroscopy (MA-WMS) for simultaneous measurement of CH4\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$\text {CH}_4$$\end{document} gas concentration and pressure was developed and validated both through simulation and experiment, showing good agreement. To capture the spectrum broadening caused by increasing pressure and concomitantly obtain the concentration at the sensor's location, a laser centered at 1650.9 nm was subjected to multiple amplitude modulation depths while the 2fm\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$2f_{m}$$\end{document} signal, normalized by the DC component (an invariant quantity under optical loss), was recorded. While the use of a single and fixed modulation can introduce an ambiguity, as different pairs of pressure and concentration can yield the same value, this ambiguity is eliminated by employing multiple amplitude modulations. In this approach, the intersection point of the three level curves can provide the local pressure and concentration. The proposed system was able to measure concentrations from 5% up to 45% and pressures from 0.25 atm up to 1.75 atm, with a maximum error of 2% in concentration and 0.06 atm in pressure, respectively. The system was also tested for attenuation insensitivity, demonstrating that measurements were not significantly affected for up to 10 dB applied optical loss.

Abstract
An all-passive, multipoint, and multiparameter optical monitoring system was developed and deployed in an industrial environment for the simultaneous measurement of methane concentration and other physical parameters. Methane is detected via rapid wavelength modulation spectroscopy (WMS) at 1648.2 nm and 4 MHz frequency. An attenuation invariant quantity defined by the peaks at 0, 4, and 8 MHz of the fast Fourier transform (FFT) of temporal signal is employed, characterized, and validated. Other parameters can concomitantly be measured by fiber Bragg grating (FBG) sensors operating in the 1520-1590 nm range. In the deployed system, the tested parameter was the temperature, which is an important quantity for gas monitoring. The system features a modular architecture that enables scalability up to 16 384 sensing points with an estimated less than 20-min acquisition cycle. In its current deployment, it monitors methane and temperature at eight locations using a single optical network. The system is intended to be used onshore and offshore platforms where the usual monitoring protocol consists of manual measurements usually performed three to four times a year and involves personal displacement and risky situations. Field tests at an onshore natural gas treatment unit (NGTU) demonstrated reliable performance and effective event detection, including undocumented nocturnal emissions, maneuvers at main shut-off valve, and partial plant shutdowns and restarts.

Abstract

Abstract

Abstract

A novel technique based on multiple amplitude wavelength modulation spectroscopy (MA-WMS) for simultaneous measurement of CH4 gas concentration and pressure was developed and validated both through simulation and experiment, showing good agreement. To capture the spectrum broadening caused by increasing pressure and concomitantly obtain the concentration at the sensor’s location, a laser centered at 1650.9 nm was subjected to multiple amplitude modulation depths while the 2fm signal, normalized by the DC component (an invariant quantity under optical loss), was recorded. While the use of a single and fixed modulation can introduce an ambiguity, as different pairs of pressure and concentration can yield the same value, this ambiguity is eliminated by employing multiple amplitude modulations. In this approach, the intersection point of the three level curves can provide the local pressure and concentration. The proposed system was able to measure concentrations from a few percentage points up to 50% and pressure from 0.02 atm up to 2 atm, with a maximum error of 2% in concentration and 0.06 atm in pressure, respectively. The system was also tested for attenuation insensitivity, demonstrating that measurements were not significantly affected for up to 10 dB applied optical loss.