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Publications

Publications by Catarina Silva Monteiro

2025

Enhancing spectral imaging with multi-condition image fusion

Authors
Teixeira, J; Lopes, T; Capela, D; Monteiro, CS; Guimaraes, D; Lima, A; Jorge, PAS; Silva, NA;

Publication
SCIENTIFIC REPORTS

Abstract
Spectral Imaging techniques such as Laser-induced Breakdown Spectroscopy (LIBS) and Raman Spectroscopy (RS) enable the localized acquisition of spectral data, providing insights into the presence, quantity, and spatial distribution of chemical elements or molecules within a sample. This significantly expands the accessible information compared to conventional imaging approaches such as machine vision. However, despite its potential, spectral imaging also faces specific challenges depending on the limitations of the spectroscopy technique used, such as signal saturation, matrix interferences, fluorescence, or background emission. To address these challenges, this work explores the potential of using techniques from conventional RGB imaging to enhance the dynamic range of spectral imaging. Drawing inspiration from multi-exposure fusion techniques, we propose an algorithm that calculates a global weight map using exposure and contrast metrics. This map is then used to merge datasets acquired with the same technique under distinct acquisition conditions. With case studies focused on LIBS and Raman Imaging, we demonstrate the potential of our approach to enhance the quality of spectral data, mitigating the impact of the aforementioned limitations. Results show a consistent improvement in overall contrast and peak signal-to-noise ratios of the merged images compared to single-condition images. Additionally, from the application perspective, we also discuss the impact of our approach on sample classification problems. The results indicate that LIBS-based classification of Li-bearing minerals (with Raman serving as the ground truth), is significantly improved when using merged images, reinforcing the advantages of the proposed solution for practical applications.

2024

Environmental Monitoring of Submarine Cable in Madeira Island

Authors
Cunha, C; Monteiro, C; Martins, HF; Silva, S; Frazao, O;

Publication
EOS ANNUAL MEETING, EOSAM 2024

Abstract
Distributed acoustic sensing (DAS) is a sensing technique that allows continuous data acquisition of strain rate and temperature with exceptional spatial resolution, up to few meters, for extensive lengths up to 100 km. The ubiquitous nature of optical fiber cables rendered DAS an appealing alternative for geophysical sensing, allowing cost-effective data collection with extensive spatial coverage leveraging existing infrastructure. This study presents findings from the deployment of a DAS system on a dark fiber located on the Madeira Island, Portugal. Through the implementation of 2D filtering, simultaneous analysis of data from road traffic, ocean waves, and seismic activity was achieved.

2025

Improving LIBS-based mineral identification with Raman imaging and spectral knowledge distillation

Authors
Lopes, T; Cavaco, R; Capela, D; Dias, F; Teixeira, J; Monteiro, CS; Lima, A; Guimaraes, D; Jorge, PAS; Silva, NA;

Publication
TALANTA

Abstract
Combining data from different sensing modalities has been a promising research topic for building better and more reliable data-driven models. In particular, it is known that multimodal spectral imaging can improve the analytical capabilities of standalone spectroscopy techniques through fusion, hyphenation, or knowledge distillation techniques. In this manuscript, we focus on the latter, exploring how one can increase the performance of a Laser-induced Breakdown Spectroscopy system for mineral classification problems using additional spectral imaging techniques. Specifically, focusing on a scenario where Raman spectroscopy delivers accurate mineral classification performance, we show how to deploy a knowledge distillation pipeline where Raman spectroscopy may act as an autonomous supervisor for LIBS. For a case study concerning a challenging Li-bearing mineral identification of spodumene and petalite, our results demonstrate the advantages of this method in improving the performance of a single-technique system. LIBS trained with labels obtained by Raman presents an enhanced classification performance. Furthermore, leveraging the interpretability of the model deployed, the workflow opens opportunities for the deployment of assisted feature discovery pipelines, which may impact future academic and industrial applications.

2024

Coreless Silica Fiber Sensor based on Self-Image Theory and coated with Graphene Oxide

Authors
Cunha, C; Monteiro, C; Vaz, A; Silva, S; Frazao, O; Novais, S;

Publication
OPTICAL SENSING AND DETECTION VIII

Abstract
This work provides a method that combines graphene oxide coating and self-image theory to improve the sensitivity of optical sensors. The sensor is designed specifically to measure the amount of glucose present quantitatively in aqueous solutions that replicate the range of glucose concentrations found in human saliva. COMSOL Multiphysics 6.0 was used to simulate the self-imaging phenomenon using a coreless silica fiber (CSF). For high-quality self-imaging, the second and fourth self-imaging points are usually preferred because of their higher coupling efficiency, which increases the sensor sensitivity. However, managing the fourth self-image is more difficult because it calls for a longer CSF length. As a result, the first and second self-image points were the focus of the simulation in this work. After the simulation, using the Layerby-Layer method, the sensor was constructed to a length that matched the second self-image point (29.12 mm) and coated with an 80 mu m/mL graphene oxide layer. When comparing uncoated and graphene oxide-covered sensors to measure glucose in liquids ranging from 25 to 200 mg/dL, one bilayer of polyethyleneimine/graphene demonstrated an eight-fold improvement in sensitivity. The final sensor, built on graphene oxide, showed stability with a low standard deviation of 0.6 pm/min. It also showed sensitivity at 10.403 +/- 0.004 pm/(mg/dL) with a limit of detection of 9.15 mg/dL.

2024

Optimizing Graphene Oxide Saturable Absorbers for Short Pulse Generation in Fiber Lasers: Characterization and Aging Assessment

Authors
Monteiro, CS; Perez-Herrera, RA; Silva, NA; Silva, SO; Frazao, O;

Publication
FIBER LASERS AND GLASS PHOTONICS: MATERIALS THROUGH APPLICATIONS IV

Abstract
The generation of short pulses in fiber lasers using saturable absorbers made of graphene oxide (GO), focusing on film thickness, was studied and optimized. The saturable absorber comprised a GO thin film deposited onto a single-mode fiber using the spray coating technique. Water-dispersed GO with a concentration of 4 mg/mL, characterized by a high proportion of monolayer flakes, was employed. This thin film was integrated into a cavity ring laser featuring an erbium-doped fiber amplifier (EDFA), resulting in a fiber laser emitting at a central emission wavelength of approximately 1564 nm and having a total cavity length of approximately 120 m. By controlling intracavity polarization, short-pulsed light was generated through mode-locking, Q switching, or a combination of both regimes. This work presents a comprehensive characterization of the cavity ring laser operating under the mode-locking regime. It encompasses an analysis of the spectral behavior, focusing on the evolution of the Kelly's sidebands with increasing pump power, as well as an assessment of its temporal stability. Moreover, the effects of the aging of the saturable absorber material were studied after a time period of 6 months after the fabrication. It was observed that the general characteristics of spectral signal of the laser were maintained, with long-term stability .

2024

Multimodal Knowledge Distillation in Spectral Imaging

Authors
Lopes, T; Capela, D; Ferreira, MFS; Teixeira, J; Silva, C; Guimaraes, DF; Jorge, PAS; Silva, NA;

Publication
OPTICAL SENSING AND DETECTION VIII

Abstract
Spectral imaging is a powerful technology that uses spatially referenced spectral signatures to create informative visual maps of sample surfaces that can reveal more than what conventional RGB-visual images can show. Indeed, different spectroscopy modalities can provide different information about the same sample: for instance, Laser-Induced Breakdown Spectroscopy (LIBS) imaging can detect the presence of specific elements on the surface, while Raman imaging can identify the molecular structures and compositions of the sample, both of which have potential applications in various industrial processes, from quality control to material sorting. In the path from science to technology, the increasing accessibility to such solutions and the strong market pull have opened a window of opportunity for innovative multimodal imaging solutions, where information from distinct sources is set to be combined in order to enhance the capabilities of the single modality system. However, the practical implementation of multimodal spectral imaging is still a challenge, despite its theoretical potential, and as such, it is yet to be achieved. In this work, we will go over multimodal spectral knowledge distillation, a disruptive approach to multimodal spectral imaging techniques that tries to explore the combination of two techniques to capitalize on their individual strengths. In specific, this approach allows us to utilize one technique as an autonomous supervisor for the other, leveraging the higher degree of knowledge and interpretability of one of the techniques to increase the performance and transparency of the other. We present some example scenarios with LIBS and HSI and Raman spectroscopy and LIBS, discussing the impact of this new approach for scientific and technological applications.

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