Abstract
High-performance computing relies on performance-oriented infrastructures with access to powerful computing resources to complete tasks that contribute to solve complex problems in society. The intensive use of resources and the increase in service demand due to emerging fields of science, combined with the exascale paradigm, climate change concerns, and rising energy costs, ultimately means that the decarbonization of these centers is key to improve their environmental and financial performance. Therefore, a review on the main opportunities and challenges for the decarbonization of high-performance computing centers is essential to help decision-makers, operators and users contribute to a more sustainable computing ecosystem. It was found that state-of-the-art supercomputers are growing in computing power, but are combining different measures to meet sustainability concerns, namely going beyond energy efficiency measures and evolving simultaneously in terms of energy and information technology infrastructure. It was also shown that policy and multiple entities are now targeting specifically HPC, and that identifying synergies with the energy sector can reveal new revenue streams, but also enable a smoother integration of these centers in energy systems. Computing-intensive users can continue to pursue their scientific research, but participating more actively in the decarbonization process, in cooperation with computing service providers. Overall, many opportunities, but also challenges, were identified, to decrease carbon emissions in a sector mostly concerned with improving hardware performance.

Abstract
In the power system decarbonization roadmap, novel grid management tools and market mechanisms are fundamental to solving technical problems concerning renewable energy forecast uncertainty. This work proposes a predictive algorithm for procurement of grid flexibility by the system operator (SO), which combines the SO flexible assets with active and reactive power short-term flexibility markets. The goal is to reduce the cognitive load of the human operator when analyzing multiple flexibility options and trajectories for the forecasted load/RES and create a human-in-the-loop approach for balancing risk, stakes, and cost. This work also formulates the decision problem into several steps where the operator must decide to book flexibility now or wait for the next forecast update (time-to-decide method), considering that flexibility (availability) price may increase with a lower notification time. Numerical results obtained for a public MV grid (Oberrhein) show that the time-to-decide method improves up to 22% a performance indicator related to a cost-loss matrix, compared to the option of booking the flexibility now at a lower price and without waiting for a forecast update.

Abstract
Green ammonia production stands as a pivotal component in the transition towards sustainable energy and agriculture, poised to revolutionize numerous industries. This paper presents an optimization control framework for industrial green ammonia fuel hubs to engage in electricity, hydrogen, and oxygen markets, addressing both economic and technical considerations. By evaluating scenarios with and without battery storage, this study demonstrates the potential for increased profitability and energy independence through secondary reserve market participation, alongside insights into the economic viability of photovoltaic investments. These findings underscore the importance of considering market dynamics and technological integration in the sustainable operation of green ammonia production hubs.

Abstract
The literature on the isothermal model gas flow is extensive, but the effect of temperature variation on the hydraulic characteristics has been rarely addressed. Additionally, the impact of hydrogen blending on the thermal condition of NG pipelines is also an emergent topic that requires new approaches to the gas flow problem formulation and resolution. In this paper, a model for the gas flow problem was developed to optimise the operation of natural gas distribution networks with hydrogen injection while maintaining pressure, gas flows, and gas quality indexes within admissible limits. The goal is to maximise the injection of hydrogen and investigate the influences of thermal variations in the gas blending. Also, this model enables the calculation of the maximum permitted volume of hydrogen in the network, quantifying the total savings in natural gas usage and carbon dioxide emissions in different temperature conditions.

Abstract
As the global community transitions towards decarbonization and sustainable energy, green hydrogen is emerging as a key clean energy carrier. This paper addresses the role of hydrogen in transportation, emphasizing the European Union's additionality principle for renewable energy sources in green hydrogen production. It introduces a model for optimally designing hydrogen fueling stations, considering electrolyzers, hydrogen storage, fuel cells, PV systems, and batteries. This model also considers the participation in electricity (energy and secondary reserve), hydrogen, and oxygen markets, and it is evaluated under different additionality policy scenarios. Results indicate that stricter additionality policies reduce the internal rate of return. However, participation in secondary reserve markets significantly boosts operational revenues and compensates for higher investment costs.

Abstract
This paper introduces a mathematical model designed to optimise the operation of natural gas distribution networks, considering the injection of hydrogen in multiple nodes. The model is designed to optimise the quantity of hydrogen injected to maintain pressure, gas flows, and gas quality indexes (Wobbe index (WI) and higher heating value (HHV)) within admissible limits. This study also presents the maximum injection allowable of hydrogen correlated with the gas quality index variation. The model has been applied to a case study of a gas network with four distinct scenarios and implemented using Python. The findings of the case study quantify the maximum permitted volume of hydrogen in the network, the total savings in natural gas, and the reduction in carbon dioxide emissions. Lastly, a sensitivity analysis of injected hydrogen as a function of the Wobbe index (WI) and Higher Heating Value (HHV) limits relaxation.