2025
Authors
dos Santos, PSS; Mendes, JP; Pastoriza-Santos, I; Juste, JP; de Almeida, JMMM; Coelho, LCC;
Publication
SENSORS AND ACTUATORS B-CHEMICAL
Abstract
The lower refractive index sensitivity (RIS) of plasmonic nanoparticles (NP) in comparison to their plasmonic thin films counterparts hindered their wide adoption for wavelength-based sensor designs, wasting the NP characteristic field locality. In this context, high aspect-ratio colloidal core-shell Ag@Au nanorods (NRs) are demonstrated to operate effectively at telecommunication wavelengths, showing RIS of 1720 nm/RIU at 1350 nm (O-band) and 2325 nm/RIU at 1550 nm (L-band), representing a five-fold improvement compared to similar Au NRs operating at equivalent wavelengths. Also, these NRs combine the superior optical performance of Ag with the Au chemical stability and biocompatibility. Next, using a side-polished optical fiber, we detected glyphosate, achieving a detection limit improvement from 724 to 85 mg/L by shifting from the O to the C/L optical bands. This work combines the significant scalability and cost-effective advantages of colloidal NPs with enhanced RIS, showing a promising approach suitable for both point-of-care and long-range sensing applications at superior performance than comparable thin film-based sensors in either environmental monitoring and other fields.
2025
Authors
Mendes, JP; dos Santosa, PSS; de Almeida, JMMM; Coelho, LCC;
Publication
29TH INTERNATIONAL CONFERENCE ON OPTICAL FIBER SENSORS
Abstract
This study investigates the fabrication of plasmonic optical fiber sensors for glyphosate detection, employing silver thin film coatings deposited via the Tollens' reaction and further enhanced with protective gold plating. Silver films were produced through electroless deposition, forming rough plasmonic surfaces with localized hotspots that amplify the electromagnetic field. Surface roughness effects on the creation of hotspots were first evaluated numerically using the finite element method (FEM) and later experimentally assessed the impact on optical response. Furthermore, to address the inherent susceptibility of silver to oxidation and corrosion, a gold plating was applied using the Kirkendall effect, selectively replacing surface silver atoms with gold. This approach significantly improved the chemical stability of the sensors while preserving their plasmonic properties. This configuration was applied in developing a biosensor, using aptamers, for detecting glyphosate in concentrations ranging from 10(-1) to 10(4) mu g/L. The results demonstrated a sensitivity of 25.08 +/- 0.22 nm/(mu g/L) and a limit of detection (LOD) of 0.04 mu g/L, nearly ten times lower than the European Union's safety limit for glyphosate. Experimental results highlight the potential of this fabrication approach for developing sensitive, stable, and scalable plasmonic sensors tailored for environmental and agricultural monitoring applications.
2025
Authors
Monteiro, CS; Ferreira, TD; Silva, NA;
Publication
OPTICS LETTERS
Abstract
Polarization optical fiber sensors are based on modifications of fiber birefringence by an external measurand (e.g., strain, pressure, acoustic waves). Yet, this means that different input states of polarization will result in very distinct behaviors, which may or may not be optimal in terms of sensitivity and signal-to-noise ratio. To tackle this challenge, this manuscript presents an optimization technique for the input polarization state using the Fisher information formalism, which allows for achieving maximal precision for a statistically unbiased metric. By first measuring the variation of the Mueller matrix of the optical fiber in response to controlled acoustic perturbations induced by piezo speakers, we compute the corresponding Fisher information operator. Using maximal information states of the Fisher information, it was possible to observe a significant improvement in the performance of the sensor, increasing the signal-to-noise ratio from 4.3 to 37.6 dB, attaining an almost flat response from 1.5 kHz up to 15 kHz. As a proof-of-concept for dynamic audio signal detection, a broadband acoustic signal was also reconstructed with significant gain, demonstrating the usefulness of the introduced formalism for high-precision sensing with polarimetric fiber sensors. (c) 2025 Optica Publishing Group. All rights, including for text and data mining (TDM), Artificial Intelligence (AI) training, and similar technologies, are reserved.
2025
Authors
Lopes, T; Teixeira, J; Rocha, VV; Ferreira, TD; Monteiro, CS; Jorge, PAS; Silva, NA;
Publication
29TH INTERNATIONAL CONFERENCE ON OPTICAL FIBER SENSORS
Abstract
Despite their extreme sensitivity, speckle-based fiber optical sensors are typically limited by the camera frame rate and dynamic range. In this context, recent developments in event-based sensors make them a promising and affordable tool for high-speed interrogation for such class of sensors, offering a low-latency approach to detecting dynamic changes in illumination patterns, well-suited for fast interrogation with frequency response up to the MHz range. In this manuscript, we investigate the potential of using an event-based vision sensor (EVS) as an interrogator for a speckle-based optical fiber sensor operating at 532nm to detect vibrations induced by an off-the-shelf sound speaker. In contact with the fiber, these vibrations induce dynamic changes in the speckle pattern, which are tracked by the EVS and processed to construct temporal frames with timestamps below 100 mu s. Approximating the differential operator of the deformation in the linear regime, we show a successful reconstruction of the acoustic signal for two illustrative case studies: i)a single-frequency signal at 1.2 KHz and ii)a linear ramp between 300 Hz to 2.5 kHz. The results demonstrate the ability to accurately identify not only the fundamental frequencies but also their harmonics generated by the speaker up to 5 KHz, paving an innovative path to harness the potential of speckle-based sensors in multiple scenarios of optical metrology and dynamic sensing applications.
2025
Authors
da Silva, PM; Mendes, JP; Coelho, LCC; de Almeida, JMMM;
Publication
29TH INTERNATIONAL CONFERENCE ON OPTICAL FIBER SENSORS
Abstract
Reinforced concrete structures form the backbone of civil infrastructure due to their durability, longevity, affordability, and availability. However, aging concrete poses challenges, with decay often beginning internally and becoming visible only at advanced stages, leading to costly repairs, restricted functionality, and safety risks. To address these challenges, sensors are crucial for enhancing infrastructure resilience and optimizing repairs. This study employs multimode optical fibers to monitor concrete curing, water ingress, relative humidity (RH), cement paste carbonation, and rebar corrosion. Four sensors monitor changes in reflection at the fiber tip of a 600 mu m multimode fiber (MMF) using LEDs and photodiodes, connected via a fiber bundle containing two 200 mu m MMF. Variations in the refractive index around the fiber tip are used to monitor water throughout the concrete lifecycle, including curing, RH changes and water intrusion. Colorimetric changes in a cement paste layer and an iron-thin film are used to monitor carbonation and corrosion. The curing sensor is temperature-independent and correlates strongly with cumulative heat release from cement hydration (R=0.95). The RH sensor monitors up to and beyond 100% RH, detecting water intrusion. The corrosion sensor detects early corrosion stages and distinguishes between reflection losses from corrosion and mechanical changes. The layer of cement paste for carbonation monitoring increases reflected intensity by 17% due to carbonation, with 63% of the increase occurring in 80 minutes in a 3% CO2 atmosphere. The broad monitoring scope and low implementation cost make this sensor a unique option among commercially available solutions for structural health monitoring of reinforced concrete.
2025
Authors
R Pereira, L; Braçais, M; Capela, D; Silva, NA; Jorge, AS; Guerner, A; Silva, SO; Frazão, O; Guimarães, D;
Publication
EPJ Web of Conferences
Abstract
A study of an Eocene fish fossil using portable XRF revealed distinct geochemical differences between the fossil and surrounding sediment. Elements like uranium, yttrium, arsenic, and phosphorus were found only in the fossil, while calcium and iron appeared in both regions. These patterns point to selective elemental incorporation during early fossilization and diagenesis processes. The results highlight XRF's usefulness in verifying fossil authenticity, provenance and understanding the chemical processes during fossilization. © 2025 Elsevier B.V., All rights reserved.
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