2022
Authors
Vasconcelos, H; Matias, A; Mendes, J; Arahjo, J; Dias, B; Jorge, PAS; Saraivaa, C; Coelho, LCC; de Almeida, JMMM;
Publication
OPTICAL SENSING AND DETECTION VII
Abstract
A strategy for the detection of H2O2 as a milk adulterant using a single shot membrane sensor, is presented. Direct quantitative evaluation of H2O2 in raw, skimmed, semi-skimmed and whole milk was carried out based on a chemiluminescence reaction with luminol. For H2O2 water solutions a linear response was attained from 0.0001% to 0.007 %w/w, with a limit of detection of 3x10(-5) %w/w. A coefficient of determination, R-2, greater than 0.97 was achieved, with a relative standard deviation (RSD) not exceeding 10%. In the analyzed milk samples, the lowest H2O2 concentration detected was 0.001% w/w for raw and for skim milk and 0.002%w/w for, semi-skimmed and whole milk. The presented method is original, sensitive, rapid, and cost-effective. Due to the achieved sensitivity the method has great potential to be used for H2O2 detection in diverse areas, such as environmental monitoring and food quality.
2022
Authors
Vasconcelos, HCASG; de Almeida, JMMM; Mendes, JP; Dias, B; Jorge, PAD; Saraiva, CMT; Coelho, LCC;
Publication
IEEE SENSORS JOURNAL
Abstract
Biogenic amines (BAs) are compounds found in a vast range of food products. In recent years, there has been a crescent awareness toward food safety, followed by an increase in food regulations. Long-period fiber gratings (LPFGs) coated with titanium dioxide (TiO2) were used to monitor the optical properties of a layer of poly(ethylene-co-vinyl acetate) (PEVA) doped with maleic anhydride (MA), which was polymerized on top of TiO2. This hydrophobic polymeric structure is permeable to BA, which causes a steady increase in its effective refractive index (RI) causing a wavelength shift in the coated LPFG attenuation band. LPFG wavelength shift was observed and measured for the monoamine tyramine (TYR), to the diamines, putrescine (PUT), cadaverine (CAD), histamine (HIS), and tryptamine (TRYP), and to the polyamines, spermidine (SPED), and spermine (SPEM). It was determined that, while PEVA-coated devices present a residual sensitivity to BA, the MA greatly increases it. In fact, for PEVA only coated LPFGs, the sensitivities of 1.45 +/- 0.11, 0.97 +/- 0.05, 0.46 +/- 0.08, and 0.94 +/- 0.09 nmM-1 for PUT, CAD, HIS, and TYR, respectively, were measured. However, for PEVA-doped MA-coated LPFGs, the sensitivities are 3.34 +/- 0.13, 3.06 +/- 0.11, 2.62 +/- 0.14, and 3.65 +/- 0.23 nmM-1 for PUT, CAD, HIS, and TYR, respectively. Thus, the RI of PEVA increases with BAs in- diffusion, and MA doping further enhances the PEVA sensitivity to BA. The proposed sensor is expected to play a part in the further development of a biosensor for the quantification of BA in real foodstuff, providing a methodology for quality control.
2022
Authors
Vasconcelos, H; De Almeida, JMMM; Mendes, J; Dias, B; Jorge, PAS; Saraiva, C; Coelho, LCC;
Publication
Optics InfoBase Conference Papers
Abstract
Long period fiber gratings coated with TiO2 and poly(ethylene-co-vinyl acetate) (PEVA), a polymeric structure permeable biogenic amines found in foodstuff, were used to detect these compounds through the wavelength shift of its attenuation band. © 2022 The Author(s).
2022
Authors
Rocha, V; Oliveira, J; Guerreiro, A; Jorge, PAS; Silva, NA;
Publication
EPJ Web of Conferences
Abstract
2022
Authors
Cavaco, R; Rodrigues, P; Lopes, T; Capela, D; Ferreira, MFS; Jorge, PAS; Silva, NA;
Publication
Journal of Physics: Conference Series
Abstract
Apart from radiation, which constitutes the primary source of information in laser-induced breakdown spectroscopy, the process is accompanied by secondary processes such as shock wave generation and sound emission. In this manuscript, we explore the possibility of relating plasma properties with the sound from the shock waves in multiple materials, from metals to minerals. By analyzing the behavior of shock wave sound from homogeneous reference metallic targets, we investigate the relation between plasma properties and sound signal, demonstrating that distinct materials and plasma characteristics correspond to distinct plasma sound fingerprints. © Published under licence by IOP Publishing Ltd.
2022
Authors
Lopes, T; Cavaco, R; Rodrigues, P; Ferreira, J; Capela, D; Ferreira, MFS; Jorge, PAS; Silva, NA;
Publication
Journal of Physics: Conference Series
Abstract
While laser-induced breakdown spectroscopy is often used as a standalone technique, recent years saw an increasing interest in their combination with additional techniques towards multimodal sensing solutions capable of enhancing the capabilities of this technological solution. In this work, we try to identify possible synergies that arise from merging the analysis of laser-induced breakdown spectroscopy with that from a hyperspectral scanning of the sample, comparing it with the performance of standalone solutions. Having investigated the multimodal approach for a case study involving the identification of lithium minerals, our preliminary results demonstrate that while both solutions can provide reasonable results for qualitative mineral identification, they feature advantages and disadvantages that shall be taken into further consideration. Nevertheless, when working in collaboration, the results enclosed suggest that an integrated tandem solution can be an interesting tool for material analysis for research and industrial applications, combining the best of both instruments. © Published under licence by IOP Publishing Ltd.
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