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Publications

Publications by CAP

2023

Low-Cost Wideband Interrogation System for Fiber Optic Sensors

Authors
Araujo, JCC; dos Santos, PSS; Dias, B; de Almeida, JMMM; Coelho, LCC;

Publication
IEEE SENSORS JOURNAL

Abstract
The interrogation of optical fiber sensors (OFS) often relies on complex devices such as optical spectrum analyzers (OSAs) that are expensive with low portability and mainly suited to laboratory measurements or dedicated interrogation systems with limited spectral range. An interrogation unit was designed and fabricated using a photodetector combined with a micro-electromechanical system and a Fabry-Perot interferometer (MEMS-FPI) working as a tunable filter with a response in the range 1350-1650 nm. Deconvolution techniques were applied to mitigate the effect of the broadband response of the tunable filter on the measured signal. The performance of the unit was validated with the interrogation of long-period fiber gratings (LPFGs) as temperature, refractive index (RI), and relative humidity (RH) sensors. For the temperature, a sensitivity of 0.135 +/- 0.007 nm/degrees C was obtained, which showed a 4.9% relative error when compared to the same measurement with an OSA. For the RI, a sensitivity of 147 +/- 11 nm/RIU was obtained, which showed a relative error lower than 1% when compared to the OSA. For the humidity, sensitivities of 0.742 +/- 0.005 and 0.056 +/- 0.006 nm/%RH were obtained, with errors of 2.75% and 6.67%, respectively, when compared to a commercial dedicated interrogation system. The low relative error obtained when compared to commercial alternatives shows the potential of the system to be used in real-time applications that require portability, low cost, energy efficiency, and capacity for integration in dedicated systems.

2023

Real-Time Monitoring of Cement Paste Carbonation with In Situ Optical Fiber Sensors

Authors
da Silva, PM; Mendes, JP; Coelho, LCC; de Almeida, JMMM;

Publication
CHEMOSENSORS

Abstract
Reinforced concrete structures are prevalent in infrastructure and are of significant economic and social importance to humanity. However, they are prone to decay from cement paste carbonation. pH sensors have been developed to monitor cement paste carbonation, but their adoption by the industry remains limited. This work introduces two new methods for monitoring cement paste carbonation in real time that have been validated through the accelerated carbonation of cement paste samples. Both configurations depart from traditional pH monitoring. In the first configuration, the carbonation depth of a cement paste sample is measured using two CO2 optical fiber sensors. One sensor is positioned on the surface of the sample, while the other is embedded in the middle. As the carbonation depth progresses and reaches the embedded CO2 sensor, the combined response of the sensors changes. In the second configuration, a multimode fiber is embedded within the paste, and its carbonation is monitored by observing the increase in reflected light intensity (1.6-18%) resulting from the formation of CaCO3. Its applicability in naturally occurring carbonation is tested at concentrations of 3.2% CO2, and the influence of water is positively evaluated; thus, this setup is suitable for real-world testing and applications.

2023

Tuning bimetallic Au@Ag nanorods Localized Surface Plasmon Resonance on side-polished optical fiber sensing configurations at near-infrared wavelengths

Authors
dos Santos, SS; Mendes, J; de Almeida, MMM; Pastoriza Santos, I; Coelho, CC;

Publication
Proceedings of SPIE - The International Society for Optical Engineering

Abstract
The increasing demand for precise chemical and biological sensing has led to the development of highly efficient plasmonic optical fiber sensors. Therefore, it is essential to optimize and match the operating wavelength region of both the optical fiber configuration and localized surface plasmon resonance of nanoparticles (NPs). This can be achieved by developing NPs that can reach resonance at near-infrared wavelengths, where refractive index sensitivity is enhanced, and silica optical fibers have lower losses. High aspect-ratio bimetallic Au@Ag nanorods and different side-polished fiber structures are tested using numerical simulations. The selected optical fiber configuration was based on a side-polished fiber with a 1 mm polished section. It is compared power losses and power at the NP interface for two configurations: a step-index single-mode fiber (SMF) with core/cladding diameters of 8.2/125 µm and a multimode graded-index fiber (GIF) with 62.5/125 µm at various polishing depths. The results showed that the best performance for both configurations was achieved at similar polishing depths, namely 59.5 and 55.2 µm for the SMF and GIF, respectively. The optical impact of retardation effects due to the proximity with the fiber structure were also observed, which caused a reduction in sensitivity from 1750 nm/RIU to 1500 nm/RIU and a red-shift of around 70 nm. © 2023 SPIE.

2023

Antimicrobial Effects and Antioxidant Activity of Myrtus communis L. Essential Oil in Beef Stored under Different Packaging Conditions

Authors
Moura, D; Vilela, J; Saraiva, S; Monteiro-Silva, F; De Almeida, JMMM; Saraiva, C;

Publication
FOODS

Abstract
The aim of this study was to assess the antimicrobial effects of myrtle (Myrtus communis L.) essential oil (EO) on pathogenic (E. coli O157:H7 NCTC 12900; Listeria monocytogenes ATCC BAA-679) and spoilage microbiota in beef and determine its minimum inhibitory concentration (MIC) and antioxidant activity. The behavior of LAB, Enterobacteriaceae, Pseudomonas spp., and fungi, as well as total mesophilic (TM) and total psychotropic (TP) counts, in beef samples, was analyzed during storage at 2 and 8 C-degrees in two different packaging systems (aerobiosis and vacuum). Leaves of myrtle were dried, its EO was extracted by hydrodistillation using a Clevenger-type apparatus, and the chemical composition was determined using chromatographical techniques. The major compounds obtained were myrtenyl acetate (15.5%), beta-linalool (12.3%), 1,8-cineole (eucalyptol; 9.9%), geranyl acetate (7.4%), limonene (6.2%), alpha-pinene (4.4%), linalyl o-aminobenzoate (5.8%), alpha-terpineol (2.7%), and myrtenol (1.2%). Myrtle EO presented a MIC of 25 mu L/mL for E. coli O157:H7 NCTC 12900, E. coli, Listeria monocytogenes ATCC BAA-679, Enterobacteriaceae, and E. coli O157:H7 ATCC 35150 and 50 mu L/mL for Pseudomonas spp. The samples packed in aerobiosis had higher counts of deteriorative microorganisms than samples packed under vacuum, and samples with myrtle EO presented the lowest microbial contents, indicating good antimicrobial activity in beef samples. Myrtle EO is a viable natural alternative to eliminate or reduce the pathogenic and deteriorative microorganisms of meat, preventing their growth and enhancing meat safety.

2023

Scalable and Cost-Effective All-Chemical Production of Stable Gold-Coated Silver Thin-Films for High-Performance Plasmonic Optical Fiber Sensors

Authors
dos Santos, SS; Mendes, P; Pastoriza Santos, I; de Almeida, MMM; Coelho, CC;

Publication
Proceedings - 28th International Conference on Optical Fiber Sensors, OFS 2023

Abstract
Long-term stability and high scalability are significant issues in plasmonic optical fiber sensors. This work presents a highly scalable and low-cost all-chemical approach for production of gold-coated silver thin-films, ensuring high performance and chemical stability. © Optica Publishing Group 2023, © 2023 The Authors.

2023

A field-based evaluation of portable XRF to screen for toxic metals in seafood products

Authors
Roberts, AA; Guimaraes, D; Tehrani, MW; Lin, S; Parsons, PJ;

Publication
X-RAY SPECTROMETRY

Abstract
Portable X-Ray Fluorescence (XRF) has become increasingly popular where traditional laboratory methods are either impractical, time consuming, and/or too costly. While the Limit of Detection (LOD) is generally poorer for XRF compared to laboratory-based methods, recent advances have improved XRF LODs and increased its potential for field-based studies. Portable XRF can be used to screen food products for toxic elements such as lead (Pb), cadmium (Cd), mercury (Hg), arsenic (As), manganese, (Mn), zinc (Zn), and strontium (Sr). In this study, 23 seafood samples were analyzed using portable XRF in a home setting. After XRF measurements were completed in each home, the same samples were transferred to the laboratory for re-analysis using microwave-assisted digestion and Inductively Coupled Plasma Tandem Mass Spectrometry (ICP-MS/MS). Four elements (Mn, Sr, As, and Zn) were quantifiable by XRF in most samples, and those results were compared to those obtained by ICP-MS/MS. Agreement was judged reasonable for Mn, Sr, and As, but not for Zn. Discrepancies could be due to (1) the limited time available to prepare field samples for XRF, (2) the heterogeneous nature of real samples analyzed by XRF, and (3) the small beam spot size (similar to 1 mm) of the XRF analyzer. Portable XRF is a cost-effective screening tool for public health investigations involving exposure to toxic metals. It is important for practitioners untrained in XRF spectrometry to (1) recognize the limitations of portable instrumentation, (2) include validation data for each specific analyte(s) measured, and (3) ensure personnel have some training in sample preparation techniques for field-based XRF analyses.

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