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Publicações

Publicações por José Almeida

2022

Development of a Low-Cost Interrogation System Using a MEMS Fabry-Pérot Tunable Filter

Autores
Araújo, JCC; Dias, B; Dos Santos, PSS; De Almeida, JMMM; Coelho, LCC;

Publicação
Journal of Physics: Conference Series

Abstract
The interrogation of optic fiber sensors usually relies in complex and costly equipment with low portability due to their size such as Optical Spectrum Analyzers (OSA) or high-resolution spectrometers. Because of this, micro spectrometer devices, such as Micro-Electromechanical Systems (MEMS) with Fabry-Pérot tunable filters, are emerging as simpler and compact alternatives capable of being used to acquire spectral information in a wide wavelength band. In this work it is described the development of an interrogation system capable of infrared spectroscopy using a MEMS Fabry-Pérot Interferometer (MEMS-FPI) with a spectral response in the 1350nm to 1650nm range. Its performance is tested with the interrogation of long period fiber gratings both as a refractive index sensor and as a temperature sensor. Deconvolution techniques such as Wiener filtering are used to reduce the impact of the tunable filter's impulse response in the measured signal. Results are comparable to those obtained using a typical OSA which shows the system's potential as a cheaper and more transportable alternative. © Published under licence by IOP Publishing Ltd.

2025

Anisotropic plasmonic nano emitters to excite surface plasmon polaritons on thin film-coated tapered optical fibers

Autores
dos Santos, PSS; Mendes, JP; Pastoriza Santos, I; de Almeida, JMMM; Coelho, LCC;

Publicação
29TH INTERNATIONAL CONFERENCE ON OPTICAL FIBER SENSORS

Abstract
The phase-matching conditions for exciting surface plasmon resonances (SPR) in plasmonic films are typically satisfied via prism, optical fibers or grating-assisted coupling. We recently showed that plasmonic nanospheres can act as local emitters, exciting SPR waves on thin films-termed nanoparticle-induced SPR (NPI-SPR). This structure holds promise for sensing, but the effects of optical fiber geometry and nanoparticle anisotropy on the response were unexplored. This study examines these factors, showing that an etched multimode fiber with a 200 mu m core diameter, taper ratio of 4, and etching angle of 20 degrees optimizes interaction with plasmonic nanoparticles. Tuning the nanoparticle aspect ratio from 1 to 3 shifts the NPI-SPR band from 780 to 1580 nm, with excitation highly dependent on the incident light angle. Notably, for light incident parallel to the film plane, a refractive index sensitivity exceeding 1000 nm/RIU is achieved. This efficient light emission combines the field locality enhancements of plasmonic nanoparticle-on-film structures with the emission efficiency of plasmonic nanoantennas, advancing plasmonic optical fiber chemical and biosensors.

2025

Optical Fiber Sensor for Glyphosate Detection Combining the Functionality of Gold and Plasmonic Properties of Silver Thin Films

Autores
Mendes, JP; dos Santosa, PSS; de Almeida, JMMM; Coelho, LCC;

Publicação
29TH INTERNATIONAL CONFERENCE ON OPTICAL FIBER SENSORS

Abstract
This study investigates the fabrication of plasmonic optical fiber sensors for glyphosate detection, employing silver thin film coatings deposited via the Tollens' reaction and further enhanced with protective gold plating. Silver films were produced through electroless deposition, forming rough plasmonic surfaces with localized hotspots that amplify the electromagnetic field. Surface roughness effects on the creation of hotspots were first evaluated numerically using the finite element method (FEM) and later experimentally assessed the impact on optical response. Furthermore, to address the inherent susceptibility of silver to oxidation and corrosion, a gold plating was applied using the Kirkendall effect, selectively replacing surface silver atoms with gold. This approach significantly improved the chemical stability of the sensors while preserving their plasmonic properties. This configuration was applied in developing a biosensor, using aptamers, for detecting glyphosate in concentrations ranging from 10(-1) to 10(4) mu g/L. The results demonstrated a sensitivity of 25.08 +/- 0.22 nm/(mu g/L) and a limit of detection (LOD) of 0.04 mu g/L, nearly ten times lower than the European Union's safety limit for glyphosate. Experimental results highlight the potential of this fabrication approach for developing sensitive, stable, and scalable plasmonic sensors tailored for environmental and agricultural monitoring applications.

2025

Hydrogen Optical Sensors Based on Magnesium Thin Films for Leak Detection in Industrial Settings

Autores
Santos, AD; de Almeida, JMMM; Mendes, JP; Almeida, MAS; Coelho, LC;

Publicação
29TH INTERNATIONAL CONFERENCE ON OPTICAL FIBER SENSORS

Abstract
Hydrogen (H-2) infrastructure is the focus of many initiatives for the planned energetic transition, but its volatility and flammability require extensive safety measures to prevent leakages and explosions. Magnesium thin films have been investigated not only for H-2 storage but also as switchable mirrors, which drastically change their optical properties when hydrogenated. Due to their lower cost compared to other hydride-forming or plasmonic metals commonly used in optical sensing, Mg-based H-2 fiber sensors have the potential to be both affordable and effective for scalable deployment in industrial settings. To this end, multilayer thin-film structures with Mg and palladium as adsorption catalyst were deposited on single-mode fiber tips, and H-2 loading/unloading processes were tested in a controlled flow gas setup. In parallel, an optical interrogation system prototype was developed, enabling fast data acquisition of fiber-tip reflectivity across multiple sensing probes at a wavelength of 1550 nm. Preliminary testing suggests fast response times of a few seconds for significant drops in reflectivity, facilitating straightforward detection of H-2 leaks using thresholding methods. Planned future work includes performance comparison with simpler sensing structures, durability and contaminant testing, and response time optimization.

2025

Optimization of Magnetoplasmonic Behavior in Ag/Fe Bilayer Nanostructures Towards Refractometric Sensing

Autores
Carvalho, JPM; Dias, BS; Coelho, LCC; de Almeida, JMMM;

Publicação
SENSORS

Abstract
Magneto-optic surface plasmon resonances (MOSPRs) rely on the interaction of magnetic fields with surface plasmon polaritons (SPP) to modulate plasmonic bands with magnetic fields and enhance magneto-optical activity. In the present work, a study on the magnetoplasmonic behavior of Ag/Fe bilayers is carried out by VIS-NIR spectroscopy and backed with SQUID measurements, determining the thickness-dependent magnetization of thin-film samples. The MOSPR sensing properties of Ag/Fe planar bilayers are simulated using Berreman's matrix formalism, from which an optimized structure composed of 15 nm of Ag and 12.5 nm of Fe is obtained. The selected structure is fabricated and characterized for refractive index (RI) sensitivity, reaching 4946 RIU-1 and returning an effective enhancement of refractometric sensitivity after magneto-optical modulation. A new optimized and cobalt-free magnetoplasmonic Ag/Fe bilayer structure is studied, fabricated, and characterized for the first time towards refractometric sensing, to the best of our knowledge. This configuration exhibits potential for enhancing refractometric sensitivity via magneto-optical modulation, thus paving the way towards a simpler, more accessible, and safe type of RI sensor with potential applications in chemical sensors and biosensors.

2025

Gold-coated silver nanorods on side-polished singlemode optical fibers for remote sensing at optical telecommunication wavelengths

Autores
dos Santos, PSS; Mendes, JP; Pastoriza-Santos, I; Juste, JP; de Almeida, JMMM; Coelho, LCC;

Publicação
SENSORS AND ACTUATORS B-CHEMICAL

Abstract
The lower refractive index sensitivity (RIS) of plasmonic nanoparticles (NP) in comparison to their plasmonic thin films counterparts hindered their wide adoption for wavelength-based sensor designs, wasting the NP characteristic field locality. In this context, high aspect-ratio colloidal core-shell Ag@Au nanorods (NRs) are demonstrated to operate effectively at telecommunication wavelengths, showing RIS of 1720 nm/RIU at 1350 nm (O-band) and 2325 nm/RIU at 1550 nm (L-band), representing a five-fold improvement compared to similar Au NRs operating at equivalent wavelengths. Also, these NRs combine the superior optical performance of Ag with the Au chemical stability and biocompatibility. Next, using a side-polished optical fiber, we detected glyphosate, achieving a detection limit improvement from 724 to 85 mg/L by shifting from the O to the C/L optical bands. This work combines the significant scalability and cost-effective advantages of colloidal NPs with enhanced RIS, showing a promising approach suitable for both point-of-care and long-range sensing applications at superior performance than comparable thin film-based sensors in either environmental monitoring and other fields.

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