2025
Autores
Carvalho, JPM; Mendes, JP; Coelho, LCC; de Almeida, JMMM;
Publicação
29TH INTERNATIONAL CONFERENCE ON OPTICAL FIBER SENSORS
Abstract
Optical fibers have been extensively applied in optical sensing platforms for their large bandwidth, stability, light weight and accessibility. This work presents a theoretical analysis of an optical fiber surface plasmon resonance system for refractometric sensing applications. The device consists of a multilayer hyperbolic metamaterial (HMM) composed of concentric Au/TiO2 alternate layers in optical fiber matrix. HMMs exhibit hyperbolic dispersion (HD) and the interaction of different plasmonic modes at each interface of the HMM is reported to enhance light-matter coupling, leading to an increased refractometric sensitivity. The HD and its effects on sensor performance are numerically investigated by effective medium theory (EMT) and backed by the exact transfer matrix method (TMM). The maximum sensor performance was attained for a configuration with 2 bilayers with 30 nm thickness for a metal fill fraction (rho) of 0.7, achieving a figure of merit (FOM) of 18.45. A direct comparison with a plasmonic Au optical fiber sensor returned an optimized FOM of 5.74, therefore achieving over a three-fold increase in sensor performance, assessing the potential of HMM as highly refractometric sensitive platforms.
2025
Autores
Carvalho, JPM; Dias, BS; Coelho, LCC; de Almeida, JMMM;
Publicação
SENSORS
Abstract
Magneto-optic surface plasmon resonances (MOSPRs) rely on the interaction of magnetic fields with surface plasmon polaritons (SPP) to modulate plasmonic bands with magnetic fields and enhance magneto-optical activity. In the present work, a study on the magnetoplasmonic behavior of Ag/Fe bilayers is carried out by VIS-NIR spectroscopy and backed with SQUID measurements, determining the thickness-dependent magnetization of thin-film samples. The MOSPR sensing properties of Ag/Fe planar bilayers are simulated using Berreman's matrix formalism, from which an optimized structure composed of 15 nm of Ag and 12.5 nm of Fe is obtained. The selected structure is fabricated and characterized for refractive index (RI) sensitivity, reaching 4946 RIU-1 and returning an effective enhancement of refractometric sensitivity after magneto-optical modulation. A new optimized and cobalt-free magnetoplasmonic Ag/Fe bilayer structure is studied, fabricated, and characterized for the first time towards refractometric sensing, to the best of our knowledge. This configuration exhibits potential for enhancing refractometric sensitivity via magneto-optical modulation, thus paving the way towards a simpler, more accessible, and safe type of RI sensor with potential applications in chemical sensors and biosensors.
2023
Autores
Carvalho, PM; Coelho, CC; Jorge, PAS; de Almeida, JMMM;
Publicação
Proceedings - 28th International Conference on Optical Fiber Sensors, OFS 2023
Abstract
Thin films of Ag/Fe were deposited on the core of multimode optical fibers. The deposited film shows sensitivity to both refractive index and MF changes. Simulation work based on TMM formalism confirms experimental response. © Optica Publishing Group 2023, © 2023 The Author(s)
2025
Autores
dos Santos, PSS; Mendes, JP; Pastoriza-Santos, I; Juste, JP; de Almeida, JMMM; Coelho, LCC;
Publicação
SENSORS AND ACTUATORS B-CHEMICAL
Abstract
The lower refractive index sensitivity (RIS) of plasmonic nanoparticles (NP) in comparison to their plasmonic thin films counterparts hindered their wide adoption for wavelength-based sensor designs, wasting the NP characteristic field locality. In this context, high aspect-ratio colloidal core-shell Ag@Au nanorods (NRs) are demonstrated to operate effectively at telecommunication wavelengths, showing RIS of 1720 nm/RIU at 1350 nm (O-band) and 2325 nm/RIU at 1550 nm (L-band), representing a five-fold improvement compared to similar Au NRs operating at equivalent wavelengths. Also, these NRs combine the superior optical performance of Ag with the Au chemical stability and biocompatibility. Next, using a side-polished optical fiber, we detected glyphosate, achieving a detection limit improvement from 724 to 85 mg/L by shifting from the O to the C/L optical bands. This work combines the significant scalability and cost-effective advantages of colloidal NPs with enhanced RIS, showing a promising approach suitable for both point-of-care and long-range sensing applications at superior performance than comparable thin film-based sensors in either environmental monitoring and other fields.
2023
Autores
dos Santos, SS; Mendes, P; Pastoriza Santos, I; de Almeida, MMM; Coelho, CC;
Publicação
Proceedings - 28th International Conference on Optical Fiber Sensors, OFS 2023
Abstract
Long-term stability and high scalability are significant issues in plasmonic optical fiber sensors. This work presents a highly scalable and low-cost all-chemical approach for production of gold-coated silver thin-films, ensuring high performance and chemical stability. © Optica Publishing Group 2023, © 2023 The Authors.
2024
Autores
Da Silva, M; Carvalho, PM; Mendes, P; De Almeida, MMM; Coelho, CC;
Publicação
EPJ Web of Conferences
Abstract
Structural health monitoring (SHM) of reinforced concrete structures (RCS) is crucial for mitigating the consequences of their deterioration. By identifying and addressing the issues early, SHM helps reduce environmental impact, safeguard lives, and enhance economic resilience. Rebar corrosion is a leading cause of early RCS decay and optical fibre sensors (OFS) have been employed for its monitoring. Reflection optrodes using optical fibres where the tip is coated with iron (Fe) thin films offer a robust, long-lasting and straightforward solution. This study investigates the tracking of spectral changes during the Fe thin film corrosion, which has been neglected in the literature, in favour of tracking reflection changes from thin film spalling. A multimode fibre tip, coated with a thin Fe layer embedded in concrete, allows spectral changes to be observed during corrosion. A 100 nm thick Fe film was deposited using radio frequency magnetron sputtering on polished fibre tips. Corrosion was induced by applying salted water drops and allowing the fibre tip to dry. Corrosion monitoring was successful for both air-exposed and cement-embedded tips, with results compared to reflection simulations of Fe, Fe2O3, and Fe2O3 thin films. This study supports monitoring at different wavelengths, enhancing robustness, cost-effectiveness and earlier detection. © The Authors.
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