Abstract
For Precise Agriculture purposes, several steps of a maize crop-system were recorded by the use of a GPS receiver with EGNOS and RTK capabilities. The field is about 35 km far from two GNSS CORS, one from RENEP, operated by IGS, and the other from SERVIR, operated by IGEoE. Both networks disseminate real-time GNSS data streams over the Internet using the NTRIP protocol. The GNSS data streams from RENEP reference stations (including validated station coordinates) provide the user with a real-time access to the ETRS89 and, those same streams from IGEoE, a military institution, are in ITRS, allowing large scale scientific applications. The validation of the EGNOS and the RTK solutions, obtained in the two TRS systems, was achieved by the results from post-processed measurements. RTK solutions, when compared to the post-processed values in the same TRS, show sub-decimeter accuracy what is enough for many of the Precision Agriculture studies. However, the two RTK solutions have a translation with a magnitude of the order of 0.5 m that can be explained by the independence of the ETRS89 on the continental drift. Indeed, at the zone where the field is located, while the ETRFyy Cartesian coordinates have velocities less than 1 mm/year, the ITRFyy Cartesian coordinates have velocities greater than 1 cm/year, what give rise to a point position variation with a magnitude of 2.5 cm/year. In order to correlate the tractor velocity, during a pre-emergence herbicide application, to the terrain slope, the field orthometric heights were obtained by the use of GRS80 ondulations, on a 1.5' x 1.5'grid, in the local Portuguese geoid model GeodPT08. The global precision of this model is estimated in 4 cm, which is within the error for the real time solutions obtained.

Abstract
Water and energy balance interactions with vegetation in mountainous terrain are influenced by topographic effects, spatial variation in vegetation type and density, and water availability. This is the case for the mountainous areas of northern Portugal, where ancestral irrigated meadows (lameiros) are a main component of a complex vegetation mosaic. The widely used surface energy balance model METRIC was applied to four Landsat images to determine the spatial and temporal distribution of the energy balance terms in the identified land cover types (LCT). A discussion on the variability of evapotranspiration (ET) through the various vegetation types was supported by a comparison between the respective crop coefficients and those available in the literature corresponding to the LC, which has shown the appropriateness of METRIC estimates of ET. METRIC products derived from images of May and June - NDVI, surface temperature, net radiation, soil heat flux, sensible heat flux, and ET - were used to characterize the LCTs, through application of principal component analysis. Three principal components explained the variance of observed variables and their varimax rotated loadings allowed a good explanation of the behaviour of the explanatory variables in association with the LCTs. Information gained contributes to improve the characterization of the study area and may further support conservation and management of these mountain landscapes.

Abstract
The conformational preferences of a series of hydroxylated isoflavones were studied by optical vibrational spectroscopy (FTIR and Raman) coupled with density functional theory (DFT) calculations. Special attention was paid to the effect of the hydroxyl substitution, due to the importance of this group in the biological activity of these systems. The isoflavones investigated - daidzein, genistein and formononetin - were shown to exist in distinct conformations in the solid state, namely regarding the orientation of the hydroxylic groups at C-7 and within the catechol moiety, that are determinant factors for their conformational behaviour and antioxidant ability. In the light of the most stable conformers obtained for each molecule, a complete assignment of their experimental vibrational spectra was performed.

Abstract
The conformational preferences of a series of hydroxyflavones were studied by Raman and FTIR spectroscopies, coupled to Density Functional Theory calculations. Special attention was paid to the effect of hydroxyl substitution, due to its importance on the biological activity of these compounds. Their conformational preferences were found to be determined mainly by the orientation of the hydroxylic groups at C-7 and within the catechol moiety, leading to the occurrence of distinct conformers in the solid state. A complete assignment of the experimental spectra was carried out for these molecules, in the light of their most stable conformers and the corresponding predicted vibrational pattern.

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