2006
Autores
Jorge, PAS; Mayeh, M; Benrashid, R; Caldas, P; Santos, JL; Farahi, F;
Publicação
MEASUREMENT SCIENCE & TECHNOLOGY
Abstract
The use of semiconductor nano-particles as temperature probes in luminescence chemical sensing applications is addressed. Temperature changes the intensity, the peak wavelength and the spectral width of the quantum dots luminescent emission in a linear and reversible way. Results are presented that show the feasibility of implementing a self-referenced intensity-based sensor to perform temperature measurements independent of the optical power level in the sensing system. A resolution of 0.3 degrees C was achieved. In addition, it is demonstrated that self-referenced temperature measurements at multiple points could be performed using reflection or transmission based optical fibre configurations.
2004
Autores
Jorge, PAS; Caldas, P; Rosa, CC; Oliva, AG; Santos, JL;
Publicação
SENSORS AND ACTUATORS B-CHEMICAL
Abstract
An optical fiber sensing system, for monitoring oxygen aiming in vivo nuclear magnetic resonance (NMR) applications is presented. Oxygen detection is based on the dynamic quenching of the fluorescence of a ruthenium complex trapped in the porous structure of a sol-gel silica film. Oxygen concentration is determined by phase-modulation fluorometry. Preliminary results concerning the characterization of doped sol-gel thin films deposited by dip coating in glass slides and in optical fiber probes are presented. Four different probe configurations are tested and compared. Best results are obtained with a fiber taper configuration which shows reproducibility and best excitation efficiency. This structure is fully characterized and some considerations regarding optimal fiber optical sensing probes for 02 detection are addressed.
2008
Autores
Jorge, PAS; Maule, C; Silva, AJ; Benrashid, R; Santos, JL; Farahi, F;
Publicação
ANALYTICA CHIMICA ACTA
Abstract
A scheme for the simultaneous determination of oxygen and temperature using quantum dots and a ruthenium complex is demonstrated. The luminescent complex [Ru(II)-tris(4,7-diphenyl-1,10-phenanthroline)](2+) is immobilized in a non-hydrolytic sol-gel matrix and used as the oxygen sensor. The temperature information is provided by the luminescent emission of core-shell CdSe-ZnS semiconductor nanocrystals immobilized in the same material. Measurements of oxygen and temperature could be performed with associated errors of +/- 2% of oxygen concentration and +/- 1 degrees C, respectively In addition, it is shown that while the dye luminescence intensity is quenched both by oxygen and temperature, the nanocrystals luminescent emission responds only to temperature. Results presented demonstrate that the combined luminescence response allows the simultaneous assessment of both parameters using a single optical fiber system. In particular, it was shown that a 10% error in the measured oxygen concentration, induced by a change in the sample temperature, could be compensated using the nanocrystals temperature information and a correction function.
2011
Autores
da Silveira, CR; Carvalho, JP; Jorge, PAS; Costa, JWA; Giraldi, MTR; Santos, JL; Carvalho Junior, EL; Figueredo, DO; Frazao, O;
Publicação
INTERNATIONAL CONFERENCE ON APPLICATIONS OF OPTICS AND PHOTONICS
Abstract
The development of an interferometric optical fiber inclinometer is described in this paper. A weak tapered region is induced in a standard single mode fiber in the vicinity of the cleaved fiber tip, using a standard fusion splicer. In this situation an in-fiber Michelson interferometer is constructed that is sensitive to curvature applied in the tapered region. It is shown that depending on the angular range, fringe visibility and/or peak position depend strongly on the applied curvature enabling low cost dielectric inclinometer to be setup that is suitable for high voltage applications. It is presented an analysis of the sensor response by means of experimental measurements and manipulation of these experimental data through computational simulations. The results coming from the numerical simulations indicate a good performance of the sensor within range of angular variation between 3 and 6 degrees and 10 and 14 degrees. A low cost strategy to interrogate the response of sensor using electrically modulated fiber Bragg gratings, a photodetector and frequency analysis is described. The results presented by this electric interrogation technique show a good sensitivity in the range 3.5 to 5.5 degrees.
2008
Autores
Caldas, P; Jorge, PAS; Araujo, F; Ferreira, LA; Rego, G; Santos, JL;
Publicação
19TH INTERNATIONAL CONFERENCE ON OPTICAL FIBRE SENSORS, PTS 1 AND 2
Abstract
In this work, an LPG-based Mach-Zehnder interferometer was evaluated as a sensing structure for environmental refractive index measurement. To interrogate this sensing device, coherence addressing and pseudo-heterodyne processing were used. The impact of stretching, bending and twisting the interferometer on the sensitivity to refractive index changes r was studied. It is shown that, due to the antisymmetric nature of cladding modes in arc-induced LPGs, it is possible to tune the system sensitivity by simple mechanical action.
2007
Autores
Jorge, PAS; Silva, AJ; Benrashid, R; Santos, JL; Farahi, F;
Publicação
Third European Workshop on Optical Fibre Sensors
Abstract
An all-optical scheme for simultaneous determination of oxygen and temperature is presented. A ruthenium complex immobilized in a non-hydrolytic sol-gel matrix is used as oxygen sensor. Temperature information is provided by CdSe quantum dots immobilized in the same material. While the dye luminescence is quenched by oxygen and temperature, the nanocrystals luminescence depends only on temperature. Results presented demonstrate that the combined luminescence response allows to simultaneously assess both parameters using a single optical fiber system.
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